Publications

374. "Synthesis and Characterization of Ir(V) Coordination Complexes with an N,O-Donor Organic Ligand", Shashi Bhushan Sinha, Dimitar Y. Shopov, Liam S. Sharninghausen, Zishan Wu, Brandon Q. Mercado, David Balcells, Gary W. Brudvig and Robert H. Crabtree (2017) Angew. Chem. Int. Ed. 56, in press.

373. "Chlorophyll a with a Farnesyl Tail in Thermophilic Cyanobacteria", Jessica M. Wiwczar, Amy M. LaFountain, Jimin Wang, Harry A. Frank and Gary W. Brudvig (2017) Photosynth. Res. 131, in press.

372. "Anchoring Groups for Photocatalytic Water Oxidation on Metal Oxide Surfaces", Kelly L. Materna, Robert H. Crabtree and Gary W. Brudvig (2017) Chem. Soc. Rev. 46, in press.

371. "Electroreduction of CO2 Catalyzed by a Heterogenized Zn-Porphyrin Complex with a Redox-Innocent Metal Center", Yueshen Wu, Jianbing Jiang, Zhe Weng, Maoyu Wang, Daniël L. J. Broere, Yiren Zhong, Gary W. Brudvig, Zhenxing Feng and Hailiang Wang (2017) ACS Cent. Sci. 3, in press.

370. "Antimony Complexes for Electrocatalysis: Activity of a Main-Group Element in Proton Reduction", Jianbing Jiang, Kelly L. Materna, Svante Hedström, Ke R. Yang, Robert H. Crabtree, Victor S. Batista and Gary W. Brudvig (2017) Angew. Chem. Int. Ed. 56, 9111-9115.

369. "Redox Activity of Oxo-Bridged Iridium Dimers in an N,O-Donor Environment: Characterization of Remarkably Stable Ir(IV,V) Complexes", Shashi Bhushan Sinha, Dimitar Y. Shopov, Liam S. Sharninghausen, Christopher J. Stein, Brandon Q. Mercado, David Balcells, Thomas Bondo Pedersen, Markus Reiher, Gary W. Brudvig and Robert H. Crabtree (2017) J. Am. Chem. Soc. 139, 9672-9683.

368. "Synthesis of Pyridine-Alkoxide Ligands for Formation of Polynuclear Complexes", Dimitar Y. Shopov, Liam S. Sharninghausen, Shashi B. Sinha, Julia E. Borowski, Brandon Q. Mercado, Gary W. Brudvig and Robert H. Crabtree (2017) New J. Chem. 41, 6709-6719.

367. "A Pomegranate-Structured Sulfur Cathode Material with Triple Confinement of Lithium Polysulfides for High-Performance Lithium-Sulfur Batteries", Yingying Mi, Wen Liu, Qian Wang, Jianbing Jiang, Gary W. Brudvig, Henghui Zhou and Hailiang Wang (2017) J. Mater. Chem. A 5, 11788-11793.

366. "Alternative Electron Acceptors for Photosystem II", Jessica Wiwczar and Gary W. Brudvig (2017) in: "Photosynthesis: Structures, Mechanisms, and Applications", Chapter 4 (Harvey J. M. Hou, Mohammad Mahdi Najafpour, Gary F. Moore and Suleyman I. Allakhverdiev, eds.) Springer Publishers, New York, pp. 51-66.

365. "Progress Towards a Molecular Mechanism of Water Oxidation in Photosystem II", David J. Vinyard and Gary W. Brudvig (2017) Annu. Rev. Phys. Chem. 68, 101-116.

364. "A Pyridine Alkoxide Chelate Ligand that Promotes Both Unusually High Oxidation States and Water-Oxidation Catalysis", Thoe K. Michaelos, Dimitar Y. Shopov, Shashi Bhushan Sinha, Liam S. Sharninghausen, Katherine J. Fisher, Hannah M. C. Lant, Robert H. Crabtree and Gary W. Brudvig (2017) Accts. Chem. Res. 50, 952-959.

363. "Electrocatalytic Water Oxidation by a Copper(II) Complex of an Oxidation-Resistant Ligand", Katherine J. Fisher, Kelly L. Materna, Brandon Q. Mercado, Robert H. Crabtree and Gary W. Brudvig (2017) ACS Catalysis 7, 3384-3387.

362. "Ultrathin Dendrimer-Graphene Oxide Composite Film for Stable Cycling Lithium-Sulfur Batteries", Wen Liu, Jianbing Jiang, Ke R. Yang, Yingying Mi, Piranavan Kumaravadivel, Yiren Zhong, Qi Fan, Zhe Weng, Zishan Wu, Judy J. Cha, Henghui Zhou, Victor S. Batista, Gary W. Brudvig and Hailiang Wang (2017) Proc. Natl. Acad. Sci. U.S.A. 114, 3578-3583.

361. "Slow Equilibration Between Spectroscopically Distinct Trap States in Reduced TiO2 Nanoparticles", Jennifer L. Peper, David J. Vinyard, Gary W. Brudvig and James M. Mayer (2017) J. Am. Chem. Soc. 139, 2868-2871.

360. "Photodriven Oxidation of Surface-Bound Iridium-Based Molecular Water-Oxidation Catalysts on Perylene-3,4-dicarboximide-Sensitized TiO2 Electrodes Protected by an Al2O3 Layer", Rebecca J. Kamire, Kelly L. Materna, William L. Hoffeditz, Brian T. Phelan, Julianne M. Thomsen, Omar K. Farha, Joseph T. Hupp, Gary W. Brudvig and Michael R. Wasielewski (2017) J. Phys. Chem. C 121, 3752-3764.

359. "Energetics of the S2 State Spin Isomers of the Oxygen-Evolving Complex of Photosystem II", David J. Vinyard, Sahr Khan, Mikhail Askerka, Victor S. Batista and Gary W. Brudvig (2017) J. Phys. Chem. B 121, 1020-1025.

358. "A Full Set of Iridium(IV) Pyridine-Alkoxide Stereoisomers: Highly Geometry-Dependent Redox Properties", Dimitar Y. Shopov, Benjamin Rudshteyn, Jesús Campos, David J. Vinyard, Victor S. Batista, Gary W. Brudvig and Robert H. Crabtree (2017) Chem. Sci. 8, 1642-1652.

357. "Insights into Photosystem II from Isomorphous Difference Fourier Maps of Femtosecond X-Ray Diffraction Data and Quantum Mechanics/Molecular Mechanics Structural Models", Jimin Wang, Mikhail Askerka, Gary W. Brudvig and Victor S. Batista (2017) ACS Energy Lett. 2, 397-407.

356. "Mechanistic Study of an Improved Ni Precatalyst for Suzuki-Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species", Megan Mohadjer Beromi, Ainara Nova, David Balcells, Ann M. Brasacchio, Gary W. Brudvig, Louise M. Guard, Nilay Hazari and David J. Vinyard (2017) J. Am. Chem. Soc. 139, 922-936.

355. "The O2-Evolving Complex of Photosystem II: Recent Insights from Quantum Mechanics/Molecular Mechanics (QM/MM), Extended X‑ray Absorption Fine Structure (EXAFS), and Femtosecond X-Ray Crystallography Data", Mikhail Askerka, Gary W. Brudvig and Victor S. Batista (2017) Accts. Chem. Res. 50, 41-48.

354. "Solvent Dependence of Lateral Charge Transfer in a Porphyrin Monolayer", Bradley J. Brennan, Kevin P. Regan, Alec C. Durrell, Charles A. Schmuttenmaer and Gary W. Brudvig (2017) ACS Energy Lett. 2, 168-173.

353. "High-Potential Porphyrins Supported on SnO2 and TiO2 Surfaces for Photoelectrochemical Applications", Jianbing Jiang, John R. Swierk, Kelly L. Materna, Svante Hedström, Shin Hee Lee, Robert H. Crabtree, Charles A. Schmuttenmaer, Victor S. Batista and Gary W. Brudvig (2016) J. Phys. Chem. C 120, 28971-28982.

352. "High Oxidation State Iridium Mono-μ-Oxo Dimers Related to Water Oxidation Catalysts", Liam S. Sharninghausen, Shashi B. Sinha, Dimitar Y. Shopov, Bonnie Choi, Brandon Q. Mercado, Xavier Roy, David Balcells, Gary W. Brudvig and Robert H. Crabtree (2016) J. Am. Chem. Soc. 138, 15917-15926.

351. "Ferrocene-Promoted Long-Cycle Lithium-Sulfur Batteries", Yingying Mi, Wen Liu, Ke R. Yang, Jianbing Jiang, Qi Fan, Zhe Weng, Yiren Zhong, Zishan Wu, Gary W. Brudvig, Victor S. Batista, Henghui Zhou and Hailiang Wang (2016) Angew. Chem. Int. Ed. 55, 14818-14822.

350. "A [3Fe-4S] Cluster is Required for tRNA Thiolation in Archaea and Eukaryotes", Yuchen Liu, David J. Vinyard, Megan E. Reesbeck, Tateki Suzuki, Kasidet Manakongtreecheep, Patrick L. Holland, Gary W. Brudvig, and Dieter Söll (2016) Proc. Natl. Acad. Sci. U.S.A. 113, 12703-12708.

349. "Heme Biomolecule as Redox Mediator and Oxygen Shuttle for Efficient Charging of Lithium-Oxygen Batteries", Won-Hee Ryu, Forrest S. Gittleson, Julianne M. Thomsen, Jinyang Li, Mark J. Schwab, Gary W. Brudvig and André D. Taylor (2016) Nature Comm. 7, 12925.

348. "One-Step Trimethylstannylation of Benzyl and Alkyl Halides", Jianbing Jiang, Robert H. Crabtree and Gary W. Brudvig (2016) J. Org. Chem. 81, 9483-9488.

347. "Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand", Thoe K. Michaelos, Hannah M. C. Lant, Liam S. Sharninghausen, Stephanie M. Craig, Fabian S. Menges, Brandon Q. Mercado, Gary W. Brudvig and Robert H. Crabtree (2016) ChemPlusChem 81, 1129-1132.

346. "Towards a Bioinspired-Systems Approach for Solar Fuel Devices", Remko J. Detz, Ken Sakai, Leone Spiccia, Gary W. Brudvig, Licheng Sun and Joost N. H. Reek (2016) ChemPlusChem 81, 1024-1027.

345. "Controlling the Rectification Properties of Molecular Junctions through Molecule−Electrode Coupling", Matthieu Koepf, Christopher Koenigsmann, Wendu Ding, Arunabh Batra, Christian F. A. Negre, Latha Venkataraman, Gary W. Brudvig, Victor S. Batista, Charles A. Schmuttenmaer and Robert H. Crabtree (2016) Nanoscale 8, 16357-16362.

344. "Structure-Function Relationships in Single Molecule Rectification by N-phenylbenzamide Derivatives", Christopher Koenigsmann, Wendu Ding, Matthieu Koepf, Arunabh Batra, Latha Venkataraman, Christian F. A. Negre, Gary W. Brudvig, Robert H. Crabtree, Victor S. Batista and Charles A. Schmuttenmaer (2016) New J. Chem. 40, 7373-7378.

343. "Rutile TiO2 as an Anode Material for Water-Splitting Dye-Sensitized Photoelectrochemical Cells", John R. Swierk, Kevin P. Regan, Jianbing Jiang, Gary W. Brudvig and Charles A. Schmuttenmaer (2016) ACS Energy Lett. 1, 603-606.

342. "Ammonia Binding in the Second Coordination Sphere of the Oxygen-Evolving Complex of Photosystem II", David J. Vinyard, Mikhail Askerka, Richard J. Debus, Victor S. Batista and Gary W. Brudvig (2016) Biochemistry 55, 4432-4436.

341. "Heterogenized Iridium Water-Oxidation Catalyst from a Silatrane Precursor", Kelly L. Materna, Benjamin Rudshteyn, Bradley J. Brennan, Morgan H. Kane, Aaron J. Bloomfield, Daria L. Huang, Dimitar Y. Shopov, Victor S. Batista, Robert H. Crabtree and Gary W. Brudvig (2016) ACS Catalysis 6, 5371-5377.

340. "Molecular Design of Light-Harvesting Photosensitizers: Effect of Varied Linker Conjugation on Interfacial Electron Transfer", Jianbing Jiang, John R. Swierk, Svante Hedström, Adam J. Matula, Robert H. Crabtree, Victor S. Batista, Charles A. Schmuttenmaer and Gary W. Brudvig (2016) Phys. Chem. Chem. Phys. 18, 18678-18682.

339. "Electrochemical CO2 Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution", Zhe Weng, Jianbing Jiang, Yueshen Wu, Zishan Wu, Xiaoting Guo, Kelly L. Materna, Wen Liu, Victor S. Batista, Gary W. Brudvig and Hailiang Wang (2016) J. Am. Chem. Soc. 138, 8076-8079.

338. "Light-Induced Water Oxidation Catalyzed by an Oxido-Bridged Triruthenium Complex with a Ru-O-Ru-O-Ru Motif", Yuta Tsubonouchi, Shu Lin, Alexander R. Parent, Gary W. Brudvig and Ken Sakai (2016) Chem. Comm. 52, 8018-8021.

337. "Surface-Induced Deprotection of THP-Protected Hydroxamic Acids on Titanium Dioxide", Bradley J. Brennan, Christopher Koenigsmann, Kelly L. Materna, Paul M. Kim, Matthieu Koepf, Robert H. Crabtree, Charles A. Schmuttenmaer and Gary W. Brudvig (2016) J. Phys. Chem. C 120, 12495-12502.

336. "Effect of Chloride Depletion on the Magnetic Properties and the Redox Leveling of the Oxygen-Evolving Complex in Photosystem II", Muhamed Amin, Ravi Pokhrel, Gary W. Brudvig, Ashraf Badawi and S. S. A. Obayya (2016) J. Phys. Chem. B 120, 4243-4248.

335. "Comparison of Heterogenized Molecular and Heterogeneous Oxide Catalysts for Photoelectrochemical Water Oxidation", Wei Li, Da He, Stafford W. Sheehan, Yumin He, James E. Thorne, Xiahui Yao, Gary W. Brudvig and Dunwei Wang (2016) Energy & Environ. Science 9, 1794-1802.

334. "Solution Structures of Highly Active Molecular Ir Water-Oxidation Catalysts from Density Functional Theory Combined with High-Energy X-Ray Scattering and EXAFS Spectroscopy", Ke R. Yang, Adam J. Matula, Gihan Kwon, Jiyun Hong, Stafford W. Sheehan, Julianne M. Thomsen, Gary W. Brudvig, Robert H. Crabtree, David M. Tiede, Lin X. Chen and Victor S. Batista (2016) J. Am. Chem. Soc. 138, 5511-5514.

333. "New Ir Bis-Carbonyl Precursor for Water Oxidation Catalysis", Daria L. Huang, Rodrigo Beltrán-Suito, Julianne M. Thomsen, Sara M. Hashmi, Kelly L. Materna, Stafford W. Sheehan, Brandon Q. Mercado, Gary W. Brudvig and Robert H. Crabtree (2016) Inorg. Chem. 55, 2427-2435.

332. "S3 State of the O2-Evolving Complex of Photosystem II: Insights from QM/MM, EXAFS and Femtosecond X-Ray Diffraction", Mikhail Askerka, Jimin Wang, David J. Vinyard, Gary W. Brudvig and Victor S. Batista (2016) Biochemistry 55, 981-984.

331. "A New Method for the Synthesis of β-Cyano Substituted Porphyrins and Their Use as Sensitizers in Photoelectrochemical Devices", A. Antoniuk-Pablant, Y. Terazono, B. J. Brennan, B. D. Sherman, J. D. Megiatto Jr., G. W. Brudvig, A. L. Moore, T. A. Moore and D. Gust (2016) J. Mater. Chem. A 4, 2976-2985.

330. "Molecular Titanium-Hydroxamate Complexes as Models for TiO2 Surface Binding", Bradley J. Brennan, Jeffrey Chen, Benjamin Rudshteyn, Subhajyoti Chaudhuri, Brandon Q. Mercado, Victor S. Batista, Robert H. Crabtree and Gary W. Brudvig (2016) Chem. Comm. 52, 2972-2975.

329. "Uncoupling Caveolae from Intracellular Signaling in vivo", Jan R. Kraehling, Zhengrong Hao, Monica Y. Lee, David J. Vinyard, Heino Velazquez, Xinran Liu, Radu V. Stan, Gary W. Brudvig and William C. Sessa (2016) Circulation Res. 118, 48-55.

328. "A Stable Coordination Complex of Rh(IV) in an N,O-donor Environment", Shashi B. Sinha, Dimitar Y. Shopov, Liam S. Sharninghausen, David J. Vinyard, Brandon Q. Mercado, Gary W. Brudvig and Robert H. Crabtree (2015) J. Am. Chem. Soc. 137, 15692-15695.

327. "Photosynthetic Water Oxidation: Binding and Activation of Substrate Waters for O–O Bond Formation", David J. Vinyard, Sahr Khan and Gary W. Brudvig (2015) Faraday Discuss. 185, 37-50.

326. "Molecular Catalysts for Water Oxidation", James D. Blakemore, Robert H. Crabtree and Gary W. Brudvig (2015) Chem. Rev. 115, 12974-13005.

325. "Computational Design of Intrinsic Molecular Rectifiers Based on Asymmetric Functionalization of N-Phenylbenzamide", Wendu Ding, Matthieu Koepf, Christopher Koenigsmann, Arunabh Batra, Latha Venkataraman, Christian F. A. Negre, Gary W. Brudvig, Robert H. Crabtree, Charles A. Schmuttenmaer and Victor S. Batista (2015) J. Chem. Theory Comput. 11, 5888-5896.

324. "Silatranes for Binding Inorganic Complexes to Metal Oxide Surfaces", Kelly L. Materna, Bradley J. Brennan and Gary W. Brudvig (2015) Dalton Trans. 44, 20312-20315.

323. "Mechanism of Manganese-Catalyzed Oxygen Evolution from Experimental and Theoretical Analyses of 18O Kinetic Isotope Effects", Sahr Khan, Ke R. Yang, Mehmed Z. Ertem, Victor S. Batista and Gary W. Brudvig (2015) ACS Catalysis 5, 7104-7113.

322. "Comparison of dppf-Supported Ni Precatalysts for the Suzuki-Miyaura Reaction: The Observation and Activity of Ni(I)", Louise M. Guard, Megan Mohadjer Beromi, Gary W. Brudvig, Nilay Hazari and David J. Vinyard (2015) Angew. Chem. Int. Ed. 54, 13352-13356.

321. "Preparation of Halogenated Fluorescent Diaminophenazine Building Blocks", Matthieu Koepf, Shin Hee Lee, Bradley J. Brennan, Dalvin D. Méndez-Hernández, Victor S. Batista, Gary W. Brudvig and Robert H. Crabtree (2015) J. Org. Chem. 80, 9881-9888.

320. "NH3 Binding to the S2 State of the O2-Evolving Complex of Photosystem II: Analog to H2O binding During the S2 → S3 Transition", Mikhail Askerka, David J. Vinyard, Gary W. Brudvig and Victor S. Batista (2015) Biochemistry 54, 5783-5786.

319. "Surfactant-Mediated Electrodeposition of a Water Oxidizing Manganese Oxide", Wojciech T. Osowiecki, Stafford W. Sheehan, Karin J. Young, Alec C. Durrell, Brandon Q. Mercado and Gary W. Brudvig (2015) Dalton Trans. 44, 16873-16881.

318. "Hematite-Based Solar Water Splitting in Acidic Solutions: Functionalization by Mono- and Multi-layers of Iridium Oxygen-Evolution Catalysts", Wei Li, Stafford W. Sheehan, Da He, Yumin He, Xiahui Yao, Ronald L. Grimm, Gary W. Brudvig and Dunwei Wang (2015) Angew. Chem. Int. Ed. 54, 11428-11432.

317. "Photoelectrochemical Cells Utilizing Tunable Corroles", Bradley J. Brennan, Yick Chong Lam, Paul M. Kim, Xing Zhang and Gary W. Brudvig (2015) ACS Appl. Mater. Interfaces 7, 16124-16130.

316. "Iridium-based Complexes for Water Oxidation", Julianne M. Thomsen, Daria L. Huang, Robert H. Crabtree and Gary W. Brudvig (2015) Dalton Trans. 44, 12452-12472.

315. "Experimental Support for a Single Electron-Transfer Oxidation Mechanism in Firefly Bioluminescence", Bruce R. Branchini, Curran E. Behney, Tara L. Southworth, Danielle M. Fontaine, Andrew M. Gulick, David J. Vinyard and Gary W. Brudvig (2015) J. Am. Chem. Soc. 137, 7592-7595.

314. "Cation Effects on the Electron-Acceptor Side of Photosystem II", Sahr Khan, Jennifer S. Sun and Gary W. Brudvig (2015) J. Phys. Chem. B 119, 7722-7728.

313. "Proton-coupled Electron Transfer During the S-state Transitions of the Oxygen-evolving Complex of Photosystem II", Muhamed Amin, Leslie Vogt, Witold Szejgis, Serguei Vassiliev, Gary W. Brudvig, Doug Bruce and M. R. Gunner (2015) J. Phys. Chem. B 119, 7366-7377.

312. "Stable Iridium(IV) Complexes of an Oxidation-Resistant Pyridine-Alkoxide Ligand: Highly Divergent Redox Properties Depending on the Isomeric Form Adopted", Dimitar Y. Shopov, Benjamin Rudshteyn, Jesús Campos, Victor S. Batista, Robert H. Crabtree and Gary W. Brudvig (2015) J. Am. Chem. Soc. 137, 7243-7250.

311. "Towards Multielectron Photocatalysis: A Porphyrin Array for Lateral Hole Transfer and Capture on a Metal Oxide Surface", Bradley J. Brennan, Alec C. Durrell, Matthieu Koepf, Robert H. Crabtree and Gary W. Brudvig (2015) Phys. Chem. Chem. Phys. 17, 12728-12734.

310. "Photosynthetic Water Oxidation: Insights from Manganese Model Chemistry", Karin J. Young, Bradley J. Brennan, Ranitendranath Tagore and Gary W. Brudvig (2015) Accts. Chem. Res. 48, 567-574.

309. "Triplet Oxygen Evolution Catalyzed by a Biomimetic Oxomanganese Complex: Functional Role of the Carboxylate Buffer", Ivan Rivalta, Ke R. Yang, Gary W. Brudvig and Victor S. Batista (2015) ACS Catalysis 5, 2384-2390.

308. "A Molecular Catalyst for Water Oxidation that Binds to Metal Oxide Surfaces", Stafford W. Sheehan, Julianne M. Thomsen, Ulrich Hintermair, Robert H. Crabtree, Gary W. Brudvig and Charles A. Schmuttenmaer (2015) Nature Comm. 6, 6469.

307. "Analysis of the Radiation-Damage-Free X-ray Structure of Photosystem II in Light of EXAFS and QM/MM Data", Mikhail Askerka, David J. Vinyard, Jimin Wang, Gary W. Brudvig and Victor S. Batista (2015) Biochemistry 54, 1713-1716.

306. "Probing the Effect of Mutations of Asparagine 181 in the D1 Subunit of Photosystem II", Ravi Pokhrel, Richard J. Debus and Gary W. Brudvig (2015) Biochemistry 54, 1663-1672.

305. "Facet-Dependent Photoelectrochemical Performance of TiO2 Nanostructures: An Experimental and Computational Study", Chuanhao Li, Christopher Koenigsmann, Wendu Ding, Benjamin Rudshteyn, Ke R. Yang, Kevin P. Regan, Steven J. Konezny, Victor S. Batista, Gary W. Brudvig, Charles A. Schmuttenmaer and Jae-Hong Kim (2015) J. Am. Chem. Soc. 137, 1520-1529.

304. "Interfacial Electron Transfer in Photoanodes Based on Phosphorus(V) Porphyrin Sensitizers Co-deposited on SnO2 with the IrIIICp* Water Oxidation Precatalyst", Prashanth K. Poddutoori, Julianne M. Thomsen, Rebecca L. Milot, Stafford W. Sheehan, Christian F. A. Negre, Venkata K. R. Garapati, Charles A. Schmuttenmaer, Victor S. Batista, Gary W. Brudvig and Art van der Est (2015) J. Mater. Chem. A 3, 3868-3879.

303. "Computational Insights on Crystal Structures of the Oxygen-Evolving Complex of Photosystem II with either Ca2+ or Ca2+ Substituted by Sr2+", Leslie Vogt, Mehmed Z. Ertem, Rhitankar Pal, Gary W. Brudvig and Victor S. Batista (2015) Biochemistry 54, 820-825.

302. "Oxygen-Evolving Complex of Photosystem II: An Analysis of Second-Shell Residues and Hydrogen-Bonding Networks", Leslie Vogt, David J. Vinyard, Sahr Khan and Gary W. Brudvig (2015) Curr. Opin. Chem. Biol. 25, 152-158.

301. "Insights into Substrate Binding to the Oxygen-Evolving Complex of Photosystem II from Ammonia Inhibition Studies", David J. Vinyard and Gary W. Brudvig (2015) Biochemistry 54, 622-628.

300. "Photoelectrochemical Hole Injection Revealed in Polyoxotitanate Nanocrystals Functionalized with Organic Adsorbates", Christian F. A. Negre, Karin J. Young, Ma. Belén Oviedo, Laura J. Allen, Cristián G. Sánchez, Katarzyna N. Jarzembska, Jason B. Benedict, Robert H. Crabtree, Philip Coppens, Gary W. Brudvig and Victor S. Batista (2014) J. Am. Chem. Soc. 136, 16420-16429.

299. "Structural Changes in the Oxygen-Evolving Complex of Photosystem II Induced by the S1 to S2 Transition: A Combined XRD and QM/MM Study", Mikhail Askerka, Jimin Wang, Gary W. Brudvig and Victor S. Batista (2014) Biochemistry 53, 6860-6862.

298. "Co(II), a Catalyst for Selective Conversion of Phenyl Rings to Carboxylic Acid Groups", Shashi Bhushan Sinha, Jesús Campos, Gary W. Brudvig and Robert H. Crabtree (2014) RSC Adv. 4, 49395-49399.

297. "Electrochemical Activation of Cp* Iridium Complexes for Electrode-Driven Water-Oxidation Catalysis", Julianne M. Thomsen, Stafford W. Sheehan, Sara M. Hashmi, Jesús Campos, Ulrich Hintermair, Robert H. Crabtree and Gary W. Brudvig (2014) J. Am. Chem. Soc. 136, 13826-13834.

296. "Substitution of a Hydroxamic Acid Anchor into the MK-2 Dye for Enhanced Photovoltaic Performance and Water Stability in a DSSC", Christopher Koenigsmann, Teresa S. Ripolles, Bradley J. Brennan, Christian F. A. Negre, Matthieu Koepf, Alec C. Durrell, Rebecca L. Milot, Jose A. Torre, Robert H. Crabtree, Victor S. Batista, Gary W. Brudvig, Juan Bisquert and Charles A. Schmuttenmaer (2014) Phys. Chem. Chem. Phys. 16, 16629-16641.

295. "Controlled Doping of Carbon Nanotubes with Metallocenes for Application in Hybrid Carbon Nanotube/Si Solar Cells", Xiaokai Li, Louise M. Guard, Jie Jiang, Kelsey Sakimoto, Jing-Shun Huang, Jianguo Wu, Jinyang Li, Lianqing Yu, Ravi Pokhrel, Gary W. Brudvig, Sohrab Ismail-Beigi, Nilay Hazari and André D. Taylor (2014) Nano Lett. 14, 3388-3394.

294. "Oxygen-Evolving Complex of Photosystem II: Correlating Structure with Spectroscopy", Ravi Pokhrel and Gary W. Brudvig (2014) Phys. Chem. Chem. Phys. 16, 11812-11821.

293. "Structural Studies of Oxomanganese Complexes for Water Oxidation Catalysis", Ivan Rivalta, Gary W. Brudvig and Victor S. Batista (2014) in: "Molecular Water Oxidation Catalysts: A Key Topic for New Sustainable Energy Conversion Schemes" (A. Llobet, ed.) John Wiley & Sons, Ltd., pp. 1-14.

292. "Nickel(I) Monomers and Dimers with Cyclopentadienyl and Indenyl Ligands", Jianguo Wu, Ainara Nova, David Balcells, Gary W. Brudvig, Wei Dai, Louise M. Guard, Nilay Hazari, Po-Heng Lin, Ravi Pokhrel and Michael K. Takase (2014) Chemistry - A European Journal 20, 5327-5337.

291. "Linker Rectifiers for Covalent Attachment of Transition-Metal Catalysts to Metal-Oxide Surfaces", Wendu Ding, Christian F. A. Negre, Julio L. Palma, Alec C. Durrell, Laura J. Allen, Karin J. Young, Rebecca L. Milot, Charles A. Schmuttenmaer, Gary W. Brudvig, Robert H. Crabtree and Victor S. Batista (2014) ChemPhysChem 15, 1138-1147.

290. "Using Site-Directed Mutagenesis to Probe the Role of the D2 Carotenoid in the Secondary Electron-Transfer Pathway of Photosystem II", Katherine E. Shinopoulos, Jianfeng Yu, Peter J. Nixon and Gary W. Brudvig (2014) Photosynth. Res. 120, 141-152.

289. "Organosilatrane Building Blocks", Bradley J. Brennan, Devens Gust and Gary W. Brudvig (2014) Tetrahedron Lett. 55, 1062-1064.

288. "Domain Structure for an Amorphous Iridium-oxide Water-Oxidation Catalyst Characterized by X‑ray Pair Distribution Function Analysis", Jier Huang, James D. Blakemore, Diego Fazi, Oleksandr Kokhan, Nathan D. Schley, Robert H. Crabtree, Gary W. Brudvig and David M. Tiede (2014) Phys. Chem. Chem. Phys. 16, 1814-1819.

287. "Photoelectrochemical Oxidation of a Turn-On Fluorescent Probe Mediated by a Surface MnII Catalyst Covalently Attached to TiO2 Nanoparticles", Alec C. Durrell, Gonghu Li, Matthieu Koepf, Karin J. Young, Christian F. A. Negre, Laura J. Allen, William R. McNamara, Hee-eun Song, Victor S. Batista, Robert H. Crabtree and Gary W. Brudvig (2014) J. Catal. 310, 37-44.

286. "S0-State Model of the Oxygen-Evolving Complex of Photosystem II", Rhitankar Pal, Christian F. A. Negre, Leslie Vogt, Ravi Pokhrel, Mehmed Z. Ertem, Gary W. Brudvig and Victor S. Batista (2013) Biochemistry 52, 7703-7706.

285. "Electron Injection Dynamics from Photoexcited Porphyrin Dyes into SnO2 and TiO2 Nanoparticles", Rebecca L. Milot, Gary F. Moore, Robert H. Crabtree, Gary W. Brudvig and Charles A. Schmuttenmaer (2013) J. Phys. Chem. C 117, 21662-21670.

284. "Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution", Jonathan Graeupner, Ulrich Hintermair, Daria L. Huang, Julianne M. Thomsen, Mike Takase, Jesús Campos, Sara M. Hashmi, Menachem Elimelech, Gary W. Brudvig and Robert H. Crabtree (2013) Organometallics 32, 5384-5390.

283. "Synthesis and Properties of NHC-Supported Palladium(I) Dimers with Bridging Allyl, Cyclopentadienyl, and Indenyl Ligands", Wei Dai, Matthew J. Chalkley, Gary W. Brudvig, Nilay Hazari, Patrick. R. Melvin, Ravi Pokhrel and Michael K. Takase (2013) Organometallics 32, 5114-5127.

282. "Complex Systems: Photosynthesis", Ravi Pokhrel and Gary W. Brudvig (2013) in: "Comprehensive Inorganic Chemistry II", Volume 3, Chapter 13, Volume on Bioinorganic Fundamentals and Applications: Metals in Natural Living Systems and Metals in Toxicology and Medicine (J. Reedijk and K. Poeppelmeier, eds. in chief; V. Pecoraro and T. Hambley, volume eds.) Elsevier, Amsterdam, The Netherlands, pp. 385-422.

281. "Precursor Transformation during Molecular Oxidation Catalysis with Organometallic Iridium Complexes", Ulrich Hintermair, Stafford W. Sheehan, Alexander R. Parent, Daniel H. Ess, David T. Richens, Patrick H. Vaccaro, Gary W. Brudvig and Robert H. Crabtree (2013) J. Am. Chem. Soc. 135, 10837-10851.

280. "Modular Assembly of High-potential Zinc Porphyrin Photosensitizers Attached to TiO2 with a Series of Anchoring Groups", Lauren A. Martini, Gary F. Moore, Rebecca L. Milot, Lawrence Z. Cai, Stafford W. Sheehan, Charles A. Schmuttenmaer, Gary W. Brudvig and Robert H. Crabtree (2013) J. Phys. Chem. C 117, 14526-14533.

279. "Mutation of Lysine 317 in the D2 Subunit of Photosystem II Alters Chloride Binding and Proton Transport", Ravi Pokhrel, Rachel J. Service, Richard J. Debus and Gary W. Brudvig (2013) Biochemistry 52, 4758-4773.

278. "An Anionic N-donor Ligand Promotes Manganese-catalyzed Water Oxidation", Karin J. Young, Michael K. Takase and Gary W. Brudvig (2013) Inorg. Chem. 52, 7615-7622.

277. "Computational Studies of the Oxygen-Evolving Complex of Photosystem II and Biomimetic Oxomanganese Complexes for Renewable Energy Applications", Ivan Rivalta, Gary W. Brudvig and Victor S. Batista (2013) ACS Sym. Ser. 1133, 203-215.

276. "Investigation of the Inhibitory Effect of Nitrite on Photosystem II", Ravi Pokhrel and Gary W. Brudvig (2013) Biochemistry 52, 3781-3789.

275. "Electrostatic Effects on Proton Coupled Electron Transfer in Oxomanganese Complexes Inspired by the Oxygen-Evolving Complex of Photosystem II", Muhamed Amin, Leslie Vogt, Serguei Vassiliev, Ivan Rivalta, Mohammad M. Sultan, Doug Bruce, Gary W. Brudvig, Victor S. Batista and M. R. Gunner (2013) J. Phys. Chem. B 117, 6217-6226.

274. "Artificial Photosynthesis as a Frontier Technology for Energy Sustainability", Thomas Faunce, Stenbjörn Styring, Michael R. Wasielewski, Gary W. Brudvig, A. William Rutherford, Johannes Messinger, Adam F. Lee, Craig L. Hill, Huub deGroot, Marc Fontecave, Douglas R. MacFarlane, Ben Hankamer, Daniel G. Nocera, David M. Tiede, Holger Dau, Warwick Hillier, Lianzhou Wang and Rose Amal (2013) Energy & Environ. Science 6, 1074-1076.

273. "Comparison of Primary Oxidants for Water-Oxidation Catalysis", Alexander R. Parent, Robert H. Crabtree and Gary W. Brudvig (2013) Chem. Soc. Rev. 42, 2247-2252.

272. "Cp* Iridium Precatalysts for Selective C−H Oxidation with Sodium Periodate as the Terminal Oxidant", Meng Zhou, Ulrich Hintermair, Brian G. Hashiguchi, Alexander R. Parent, Sara M. Hashmi, Menachem Elimelech, Roy A. Periana, Gary W. Brudvig and Robert H. Crabtree (2013) Organometallics 32, 957-965.

271. "Characterization of an Amorphous Iridium Water-Oxidation Catalyst Electrodeposited from Organometallic Precursors", James D. Blakemore, Michael W. Mara, Maxwell N. Kushner-Lenhoff, Nathan D. Schley, Steven J. Konezny, Ivan Rivalta, Christian F. A. Negre, Robert C. Snoeberger III, Oleksandr Kokhan, Jier Huang, Andrew Stickrath, Lan Anh Tran, Maria L. Parr, Lin X. Chen, David M. Tiede, Victor S. Batista, Robert H. Crabtree and Gary W. Brudvig (2013) Inorg. Chem. 52, 1860-1871.

270. "Effects of Aqueous Buffers on Electrocatalytic Water Oxidation with an Iridium Oxide Material Electrodeposited in Thin Layers from an Organometallic Precursor", Maxwell N. Kushner-Lenhoff, James D. Blakemore, Nathan D. Schley, Robert H. Crabtree and Gary W. Brudvig (2013) Dalton Trans. 42, 3617-3622.

269. "Plasmonic Enhancement of Dye-Sensitized Solar Cells using Core-Shell-Shell Nanostructures", Stafford W. Sheehan, Heeso Noh, Gary W. Brudvig, Hui Cao and Charles A. Schmuttenmaer (2013) J. Phys. Chem. C 117, 927-934.

268. "Photosystem II", Iain L. McConnell and Gary W. Brudvig (2013) in: "Encyclopedia of Biophysics", Volume on Electron Transfer (G. C. K. Roberts, ed. in chief; V. Davidson, volume ed.) Springer, pp. 1879-1882.

267. "Electron-Rich CpIr(biphenyl-2,2'-diyl) Complexes with π-Accepting Carbon Donor Ligands", Jonathan Graeupner, Timothy P. Brewster, James D. Blakemore, Nathan D. Schley, Julianne M. Thomsen, Gary W. Brudvig, Nilay Hazari and Robert H. Crabtree (2012) Organometallics 31, 7158-7164.

266. "Ultrafast Photodriven Intramolecular Electron Transfer to Perylene Diimide Derivatives from an Iridium-Based Water-Oxidation Catalyst", Michael T. Vagnini, Amanda L. Smeigh, James D. Blakemore, Samuel W. Eaton, Nathan D. Schley, Francis D'Souza, Robert H. Crabtree, Gary W. Brudvig, Dick T. Co and Michael R. Wasielewski (2012) Proc. Natl. Acad. Sci. U.S.A. 109, 15651-15656.

265. "Light-driven Water Oxidation for Solar Fuels", Karin J. Young, Lauren A. Martini, Rebecca L. Milot, Robert C. Snoeberger III, Victor S. Batista, Charles A. Schmuttenmaer, Robert H. Crabtree and Gary W. Brudvig (2012) Coord. Chem. Rev. 256, 2503-2520.

264. "Organometallic Ni Pincer Complexes for the Electrocatalytic Production of Hydrogen", Oana R. Luca, James D. Blakemore, Steven J. Konezny, Jeremy M. Praetorius, Timothy J. Schmeier, Glendon B. Hunsinger, Victor S. Batista, Gary W. Brudvig, Nilay Hazari and Robert H. Crabtree (2012) Inorg. Chem. 51, 8704−8709.

263. "Comparison of Amorphous Iridium Water-Oxidation Electrocatalysts Prepared from Soluble Precursors", James D. Blakemore, Nathan D. Schley, Maxwell N. Kushner-Lenhoff, Andrew M. Winter, Francis D'Souza, Robert H. Crabtree and Gary W. Brudvig (2012) Inorg. Chem. 51, 7749-7763.

262. "Synthesis and Computational Studies of Mg Complexes Supported by 2,2':6,2''-Terpyridine Ligands", Louise M. Guard, Julio L. Palma, William P. Stratton Laura J. Allen, Gary W. Brudvig, Robert H. Crabtree, Victor S. Batista and Nilay Hazari (2012) Dalton Trans. 41, 8098-8110.

261. "Aqueous Speciation and Electrochemical Properties of a Water-Soluble Manganese Phthalocyanine Complex", James D. Blakemore, Jonathan F. Hull, Robert H. Crabtree and Gary W. Brudvig (2012) Dalton Trans. 41, 7681-7688.

260. "Sodium Periodate as a Primary Oxidant for Water-Oxidation Catalysts", Alexander R. Parent, Timothy P. Brewster, Wendy De Wolf, Robert H. Crabtree and Gary W. Brudvig (2012) Inorg. Chem. 51, 6147-6152.

259. "Interfacial Electron Transfer into Functionalized Crystalline Polyoxotitanate Nanoclusters", Robert C. Snoeberger III, Karin J. Young, Jiji Tang, Laura J. Allen, Robert H. Crabtree, Gary W. Brudvig, Philip Coppens, Victor S. Batista and Jason B. Benedict (2012) J. Am. Chem. Soc. 134, 8911-8917.

258. "A Tridentate Ni Pincer for Aqueous Electrocatalytic Hydrogen Production", Oana R. Luca, Steven J. Konezny, James D. Blakemore, Dominic M. Colosi, Shubhro Saha, Gary W. Brudvig, Victor S. Batista and Robert H. Crabtree (2012) New J. Chem. 36, 1149-1152.

257. "Oxomanganese Complexes for Natural and Artificial Photosynthesis", Ivan Rivalta, Gary W. Brudvig and Victor S. Batista (2012) Curr. Opin. Chem. Biol. 16, 11-18.

256. "Water Oxidation Catalyzed by the Tetranuclear Mn Complex: [MnIV4O5(terpy)4(H2O)2](ClO4)6", Yunlong Gao, Robert H. Crabtree and Gary W. Brudvig (2012) Inorg. Chem. 51, 4043-4050.

255. "Bioinspired High-Potential Porphyrin Photoanodes", Gary F. Moore, Steven J. Konezny, Hee-eun Song, Rebecca L. Milot, James D. Blakemore, Minjoo L. Lee, Victor S. Batista, Charles A. Schmuttenmaer, Robert H. Crabtree and Gary W. Brudvig (2012) J. Phys. Chem. C 116, 4892-4902.

254. "EPR-ENDOR Characterization of (17O, 1H, 2H) Water in Manganese Catalase and its Relevance to the Oxygen-Evolving Complex of Photosystem II", Iain L. McConnell, Vladimir M. Griogoryants, Charles P. Scholes, William K. Myers, Ping-Yu Chen, James W. Whittaker and Gary W. Brudvig (2012) J. Am. Chem. Soc. 134, 1504-1512.

253. "Cytochrome b559 and Cyclic Electron Transfer Within Photosystem II", Katherine E. Shinopoulos and Gary W. Brudvig (2012) Biochim. Biophys. Acta 1817, 66-75.

252. "Wilkinson's Iridium Acetate Trimer as a Water-Oxidation Catalyst", Alexander R. Parent, James D. Blakemore, Gary W. Brudvig and Robert H. Crabtree (2011) Chem. Comm. 47, 11745-11747.

251. "Photocatalytic Water Oxidation Using Manganese Compounds Immobilized in Nafion Polymer Membranes", Karin J. Young, Yunlong Gao and Gary W. Brudvig (2011) Australian J. Chem. 64, 1219-1226.

250. "Redirecting Electron Transfer in Photosystem II from Water to Redox-active Metal Complexes", Gözde Ulas and Gary W. Brudvig (2011) J. Am. Chem. Soc. 133, 13260-13263.

249. "Fluctuation-Induced Tunneling Conductivity in Nanoporous TiO2 Films", Steven J. Konezny, Christiaan Richter, Robert C. Snoeberger III, Alexander R. Parent, Gary W. Brudvig, Charles A. Schmuttenmaer and Victor S. Batista (2011) J. Phys. Chem. Lett. 2, 1931-1936.

248. "Structural-Functional Role of Chloride in Photosystem II", Ivan Rivalta, Muhamed Amin, Sandra Luber, Serguei Vassiliev, Ravi Pokhrel, Yasufumi Umena, Keisuke Kawakami, Jian-Ren Shen, Nobuo Kamiya, Doug Bruce, Gary W. Brudvig, M. R. Gunner and Victor S. Batista (2011) Biochemistry 50, 6312-6315.

247. "S1-State Model of the O2-Evolving Complex of Photosystem II", Sandra Luber, Ivan Rivalta, Yasufumi Umena, Keisuke Kawakami, Jian-Ren Shen, Nobuo Kamiya, Gary W. Brudvig and Victor S. Batista (2011) Biochemistry 50, 6308-6311.

246. "Distinguishing Homogeneous from Heterogeneous Catalysis in Electrode-Driven Water Oxidation with Molecular Iridium Catalysts", Nathan D. Schley, James D. Blakemore, Navaneetha K. Subbaiyan, Christopher D. Incarvito, Francis D'Souza, Robert H. Crabtree and Gary W. Brudvig (2011) J. Am. Chem. Soc. 133, 10473-10481.

245. "A Visible Light Water-Splitting Cell with a Photoanode formed by Codeposition of a High-Potential Porphyrin and an Iridium Water-Oxidation Catalyst", Gary F. Moore, James D. Blakemore, Rebecca L. Milot, Jonathan F. Hull, Hee-eun Song, Lawrence Cai, Charles A. Schmuttenmaer, Robert H. Crabtree and Gary W. Brudvig (2011) Energy Environ. Science 4, 2389-2392.

244. "Photodamage of a Mn(III/IV)-oxo Mixed-Valence Compound and Photosystem II: Evidence That a High-Valent Manganese Species Is Responsible for UV-induced Photodamage of the Oxygen-Evolving Complex in Photosystem II", Zi Wei, Clyde W. Cady, Gary W. Brudvig and Harvey J. M. Hou (2011) J. Photochem. Photobiol. B 104, 118-125.

243. "Biocompatible and pH-Sensitive PLGA Encapsulated MnO Nanocrystals for Molecular and Cellular MRI", Margaret F. Bennewitz, Tricia L. Lobo, Michael K. Nkansah, Gözde Ulas, Gary W. Brudvig and Erik M. Shapiro (2011) ACS Nano 5, 3438-3446.

242. "Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement", Robert E. Blankenship, David M. Tiede, James Barber, Gary W. Brudvig, Graham Fleming, Maria Ghirardi, M. R. Gunner, Wolfgang Junge, David M. Kramer, Anastasios Melis, Thomas A. Moore, Christopher C. Moser, Daniel G. Nocera, Arthur J. Nozik, Donald R. Ort, William W. Parson, Roger C. Prince and Richard T. Sayre (2011) Science 332, 805-809.

241. "Chloride Regulation of Enzyme Turnover: Application to the Role of Chloride in Photosystem II", Ravi Pokhrel, Iain L. McConnell and Gary W. Brudvig (2011) Biochemistry 50, 2725-2734.

240. "An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+, Related to a Water-Oxidation Catalyst", Timothy P. Brewster, James D. Blakemore, Nathan D. Schley, Christopher D. Incarvito, Nilay Hazari, Gary W. Brudvig and Robert H. Crabtree (2011) Organometallics 30, 965-973.

239. "Energy Conversion in Photosynthesis: A Paradigm for Solar Fuel Production", Gary F. Moore and Gary W. Brudvig (2011) Annu. Rev. Condensed Matter Phys. 2, 303-327.

238. "Thermal Stability of [Mn(III)(O)2Mn(IV)(H2O)2(Terpy)2](NO3)3 (Terpy = 2,2':6',2"- terpyridine) in Aqueous Solution", Fan Zhang, Clyde W. Cady, Gary W. Brudvig and Harvey J. M. Hou (2011) Inorg. Chim. Acta 366, 128-133.

237. "Anodic Deposition of a Robust Iridium Water-Oxidation Catalyst from Organometallic Precursors", James D. Blakemore, Nathan D. Schley, Gerard W. Olack, Christopher D. Incarvito, Gary W. Brudvig and Robert H. Crabtree (2011) Chemical Science 2, 94-98.

236. "Reversible Visible-Light Photooxidation of an Oxomanganese Water-Oxidation Catalyst Covalently Anchored to TiO2 Nanoparticles", Gonghu Li, Eduardo M. Sproviero, William R. McNamara, Robert C. Snoeberger III, Robert H. Crabtree, Gary W. Brudvig and Victor S. Batista (2010) J. Phys. Chem. B 114, 14214-14222.

235. "Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis", James D. Blakemore, Nathan D. Schley, David Balcells, Jonathan F. Hull, Gerard W. Olack, Christopher D. Incarvito, Odile Eisenstein, Gary W. Brudvig and Robert H. Crabtree (2010) J. Am. Chem. Soc. 132, 16017-16029.

234. "Zwitterion Modulation of O2-Evolving Activity of Cyanobacterial Photosystem II", Gözde Ulas and Gary W. Brudvig (2010) Biochemistry 49, 8220-8227.

233. "Energy Conversion in Photosynthesis", Gözde Ulas and Gary W. Brudvig (2010) in: "Energy Production and Storage – Inorganic Chemical Strategies for a Warming World" (R. H. Crabtree, ed.) John Wiley & Sons, Ltd., pp. 21-33.

232. "Study of Proton Coupled Electron Transfer in a Biomimetic Dimanganese Water Oxidation Catalyst with Terminal Water Ligands", Ting Wang, Gary W. Brudvig and Victor S. Batista (2010) J. Chem. Theory Comput. 6, 2395-2401.

231. "Water-Stable, Hydroxamate Anchors for Functionalization of TiO2 Surfaces with Ultrafast Interfacial Electron Transfer", William R. McNamara, Rebecca L. Milot, Hee-eun Song, Robert C. Snoeberger III, Victor S. Batista, Charles A. Schmuttenmaer, Gary W. Brudvig and Robert H. Crabtree (2010) Energy Environ. Science 3, 917-923.

230. "Manganese Catalysts for C—H activation: An Experimental/Theoretical Study Identifies the Stereoelectronic Factor that Controls the Switch between Hydroxylation and Desaturation Pathways", Jonathan F. Hull, David Balcells, Effiette L. O. Sauer, Christophe Raynaud, Gary W. Brudvig, Robert H. Crabtree and Odile Eisenstein (2010) J. Am. Chem. Soc. 132, 7605-7616.

229. "Energy Conversion in Natural and Artificial Photosynthesis", Iain McConnell, Gonghu Li and Gary W. Brudvig (2010) Chemistry & Biology 17, 434-447.

228. "[(H2O)(terpy)Mn(μ-O)2Mn(terpy)(OH2)](NO3)3 (terpy = 2,2':6,2"-Terpyridine) and its Relevance to the Oxygen-Evolving Complex of Photosystem II Examined Through pH Dependent Cyclic Voltammetry", Clyde W. Cady, Katherine E. Shinopoulos, Robert H. Crabtree and Gary W. Brudvig (2010) Dalton Trans. 39, 3985-3989.

227. "Characterization of Proton Coupled Electron Transfer in a Biomimetic Oxomanganese Complex: Evaluation of the DFT/B3LYP Level of Theory", Ting Wang, Gary Brudvig and Victor S. Batista (2010) J. Chem. Theory Comput. 6, 755-760.

226. "Direct Detection of Oxygen Ligation to the Mn4Ca Cluster of Photosystem II by X-ray Emission Spectroscopy", Yulia Pushkar, Xi Long, Pieter Glatzel, Gary W. Brudvig, G. Charles Dismukes, Terrence J. Collins, Vittal K. Yachandra, Junko Yano and Uwe Bergmann (2010) Angew. Chem. 49, 800-803.

225. "The MoD-QM/MM Methodology for Structural Refinement of Photosystem II and Other Biological Macromolecules", Eduardo M. Sproviero, Michael B. Newcomer, José A. Gascón, Enrique R. Batista, Gary W. Brudvig and Victor S. Batista (2009) Photosynth. Res. 102, 455-470.

224. "Synergistic Effect between Anatase and Rutile TiO2 Nanoparticles in Dye-Sensitized Solar Cells", Gonghu Li, Christiaan P. Richter, Rebecca L. Milot, Lawrence Cai, Charles A. Schmuttenmaer, Robert H. Crabtree, Gary W. Brudvig and Victor S. Batista (2009) Dalton Trans., 10078-10085.

223. "Hydroxamate Anchors for Water-Stable Attachment to TiO2 Nanoparticles", William R. McNamara, Robert C. Snoeberger III, Gonghu Li, Christiaan Richter, Laura J. Allen, Rebecca L. Milot, Charles A. Schmuttenmaer, Robert H. Crabtree, Gary W. Brudvig and Victor S. Batista (2009) Energy Environ. Science 2, 1173-1175.

222. "Molecular Recognition in Mn-Catalyzed C-H Oxidation. Reaction Mechanism and Origin of Selectivity from a DFT Perspective", David Balcells, Pamela Moles, James D. Blakemore, Christophe Raynaud, Gary W. Brudvig, Robert H. Crabtree and Odile Eisenstein (2009) Dalton Trans., 5989-6000.

221. "Formation of Carotenoid Neutral Radicals in Photosystem II", Yunlong Gao, Katherine E. Shinopoulos, Cara A. Tracewell, A. Ligia Focsan, Gary W. Brudvig and Lowell D. Kispert (2009) J. Phys. Chem. B 113, 9901-9908.

220. "Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation", Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W. Brudvig and Robert H. Crabtree (2009) J. Am. Chem. Soc. 131, 8730-8731.

219. "In-situ Dimanganese Catalyst for Fast Screening of Molecular Recognition Catalysts for Regioselective Oxygenation of an sp3 C-H Bond", Siddhartha Das, Gary W. Brudvig and Robert H. Crabtree (2009) Inorg. Chim. Acta 362, 1229-1233.

218. "Deposition of an Oxomanganese Water Oxidation Catalyst on TiO2 Nanoparticles: Computational Modeling, Assembly and Characterization", Gonghu Li, Eduardo M. Sproviero, Robert C. Snoeberger III, Nobuhito Iguchi, James D. Blakemore, Robert H. Crabtree, Gary W. Brudvig and Victor S. Batista (2009) Energy Environ. Science 2, 230-238.

217. "Manganese Catalysts with Molecular Recognition Functionality for Selective Alkene Epoxidation", Jonathan F. Hull, Effiette L. O. Sauer, Christopher D. Incarvito, J. W. Faller, Gary W. Brudvig and Robert H. Crabtree (2009) Inorg. Chem. 48, 488-495.

216. "Characterization of the Secondary Electron-Transfer Pathway Intermediates of Photosystem II Containing Low-Potential Cytochrome b559", Cara A. Tracewell and Gary W. Brudvig (2008) Photosynth. Res. 98, 189-197.

215. "Redox Reactions of the Non-Heme Iron in Photosystem II: An EPR Spectroscopic Study", James P. McEvoy and Gary W. Brudvig (2008) Biochemistry 47, 13394-13403.

214. "Multiple Redox-Active Chlorophylls in the Secondary Electron-Transfer Pathways of Oxygen-Evolving Photosystem II", Cara A. Tracewell and Gary W. Brudvig (2008) Biochemistry 47, 11559-11572.

213. "Acetylacetonate Anchors for Robust Functionalizaion of TiO2 Nanoparticles with Mn(II)-terpyridine Complexes", William R. McNamara, Robert C. Snoeberger III, Gonghu Li, James M. Schleicher, Clyde W. Cady, Macarena Poyatos, Charles A. Schmuttenmaer, Robert H. Crabtree, Gary W. Brudvig and Victor S. Batista (2008) J. Am. Chem. Soc. 130, 14329-14338.

212. "Characterization of Siloxane Adsorbates Covalently Attached to TiO2", Nobuhito Iguchi, Clyde Cady, Robert C. Snoeberger III, Bryan M. Hunter, Eduardo M. Sproviero, Charles A. Schmuttenmaer, Robert H. Crabtree, Gary W. Brudvig and Victor S. Batista (2008) Proc. of SPIE 7034, 70340C1-8.

211. "Computational Insights into the O2-Evolving Complex of Photosystem II", Eduardo M. Sproviero, James P. McEvoy, José A. Gascón, Gary W. Brudvig and Victor S. Batista (2008) Photosynth. Res. 97, 91-114.

210. "A Model of the Oxygen-Evolving Center of Photosystem II Predicted by Structural Refinement Based on EXAFS Simulations", Eduardo M. Sproviero, José A. Gascón, James P. McEvoy, Gary W. Brudvig and Victor S. Batista (2008) J. Am. Chem. Soc. 130, 6728-6730.

209. "Quantum Mechanics/Molecular Mechanics Study of the Catalytic Cycle of Water Splitting in Photosystem II", Eduardo M. Sproviero, José A. Gascón, James P. McEvoy, Gary W. Brudvig and Victor S. Batista (2008) J. Am. Chem. Soc. 130, 3428-3442.

208. "Oxygen Evolution Catalysis by a Dimanganese Complex and Its Relation to Photosynthetic Water Oxidation", Ranitendranath Tagore, Robert H. Crabtree and Gary W. Brudvig (2008) Inorg. Chem. 47, 1815-1823.

207. "Evidence Against Bicarbonate Bound in the O2-Evolving Complex of Photosystem II", Gözde Ulas, Gerard Olack and Gary W. Brudvig (2008) Biochemistry 47, 3073-3075.

206. "Water Oxidation Chemistry of Photosystem II", Gary W. Brudvig (2008) Phil. Trans. R. Soc. Lond. B 363, 1211-1219.

205. "QM/MM Computational Studies of Substrate Water Binding to the Oxygen-Evolving Centre of Photosystem II", Eduardo M. Sproviero, Katherine Shinopoulos, José A. Gascón, James P. McEvoy, Gary W. Brudvig and Victor S. Batista (2008) Phil. Trans. R. Soc. Lond. B 363, 1149-1156.

204. "High Turnover Remote Catalytic Oxygenation of Alkyl Groups: How Steric Exclusion of Unbound Substrate Contributes to High Molecular Recognition Selectivity", Siddhartha Das, Gary W. Brudvig and Robert H. Crabtree (2008) J. Am. Chem. Soc. 130, 1628-1637.

203. "Efficient Coupling of Catalysis and Dynamics in the E1 Component of Escherichia coli Pyruvate Dehydrogenase Multienzyme Complex", Sachin Kale, Gözde Ulas, Jaeyoung Song, Gary W. Brudvig, William Furey and Frank Jordan (2008) Proc. Natl. Acad. Sci. U.S.A. 105, 1158-1163.

202. "Functional Models for the Oxygen-Evolving Complex of Photosystem II", Clyde W. Cady, Robert H. Crabtree and Gary W. Brudvig (2008) Coord. Chem. Rev. 252, 444-455.

201. "Computational Studies of the O2-Evolving Complex of Photosystem II and Biomimetic Oxomanganese Complexes", Eduardo M. Sproviero, José A. Gascón, James P. McEvoy, Gary W. Brudvig and Victor S. Batista (2008) Coord. Chem. Rev. 252, 395-415.

200. "Functional Manganese Model Chemistry Relevant to the Oxygen-Evolving Complex of Photosystem II: Oxidation of aMn(III,IV) Complex Coupled to Deprotonation of a Terminal Water Ligand", Clyde W. Cady, Robert H. Crabtree and Gary W. Brudvig (2008) in: "Photosynthesis. Energy from the Sun: 14th International Congress on Photosynthesis", (J. F. Allen, E. Gantt, J. H. Golbeck and B. Osmond, eds.) Springer Publishers, New York, pp. 377-381.

199. "Ligation of the C-Terminus of the D1 Polypeptide of Photosystem II to the Oxygen Evolving Complex: A DFT-QM/MM Study", José A. Gascón, Eduardo M. Sproviero, James P. McEvoy, Gary W. Brudvig and Victor S. Batista (2008) in: "Photosynthesis. Energy from the Sun: 14th International Congress on Photosynthesis", (J. F. Allen, E. Gantt, J. H. Golbeck and B. Osmond, eds.) Springer Publishers, New York, pp. 363-368.

198. "Redox Reactions of the Non-Heme Iron of Photosystem II: An EPR Spectroscopic Study", James P. McEvoy and Gary W. Brudvig (2008) in: "Photosynthesis. Energy from the Sun: 14th International Congress on Photosynthesis", (J. F. Allen, E. Gantt, J. H. Golbeck and B. Osmond, eds.) Springer Publishers, New York, pp. 141-144.

197. "Molecular Recognition in Homogeneous Transition Metal Catalysis: A Biomimetic Strategy for High Selectivity", Siddhartha Das, Gary W. Brudvig and Robert H. Crabtree (2008) Chem. Comm., 413-424.

196. "Hyperfine Coupling to the Bridging 17O in the Di-μ-oxo Core of a MnIII-MnIV Model Significant to the Core Electronic Structure of the O2-Evolving Complex in Photosystem II", Oleg M. Usov, Vladimir M. Grigoryants, Ranitendranath Tagore, Gary W. Brudvig and Charles P. Scholes (2007) J. Am. Chem. Soc. 129, 11886-11887.

195. "Ultrafast Photooxidation of a Mn(II)-terpyridine Complex Attached to TiO2 Nanoparticles", Sabas G. Abuabara, Clyde W. Cady, Jason B. Baxter, Charles A. Schmuttenmaer, Robert H. Crabtree, Gary W. Brudvig and Victor S. Batista (2007) J. Phys. Chem. C 111, 11982-11990.

194. "Measuring Distances in Proteins by Saturation-Recovery EPR", Donald J. Hirsh and Gary W. Brudvig (2007) Nature Protocols 2, 1770-1781.

193. "Homogeneous Water Oxidation by a Di-μ-Oxo Dimanganese Complex in the Presence of Ce4+", Ranitendranath Tagore, Hongyu Chen, Hong Zhang, Robert H. Crabtree and Gary W. Brudvig (2007) Inorg. Chim. Acta 360, 2983-2989.

192. "Quantum Mechanics/Molecular Mechanics Structural Models of the Oxygen-Evolving Complex of Photosystem II", Eduardo M. Sproviero, José A. Gascón, James P. McEvoy, Gary W. Brudvig and Victor S. Batista (2007) Curr. Opin. Struct. Biol. 17, 173-180.

191. "Probing the Functional Role of Ca2+ in the Oxygen-Evolving Complex of Photosystem II by Metal Ion Inhibition", Cheng-I Lee, K. V. Lakshmi and Gary W. Brudvig (2007) Biochemistry 46, 3211-3223.

190. "Distinct Mechanisms of Bridging-oxo Exchange in Di-μ-O Di-Manganese Complexes With and Without Water Binding Sites: Implications for Water Binding in the O2-Evolving Complex of Photosystem II", Ranitendranath Tagore, Robert H. Crabtree and Gary W. Brudvig (2007) Inorg. Chem. 46, 2193-2203.

189. "Speciation of the Catalytic Oxygen Evolution System: [MnIII/IV2(μ-O)2(terpy)2(H2O)2](NO3)3 + HSO5-", Hongyu Chen, Ranitendranath Tagore, Gerard Olack, John S. Vrettos, Tsu-Chien Weng, James Penner-Hahn, Robert H. Crabtree and Gary W. Brudvig (2007) Inorg. Chem. 46, 34-46.

188. "Water-Splitting Chemistry of Photosystem II", James P. McEvoy and Gary W. Brudvig (2006) Chem. Rev. 106, 4455-4483.

187. "Determination of μ-oxo Exchange Rates in Di-μ-oxo Dimanganese Complexes by Electrospray Ionization Mass Spectrometry", Ranitendranath Tagore, Hongyu Chen, Robert H. Crabtree and Gary W. Brudvig (2006) J. Am. Chem. Soc. 128, 9457-9465.

186. "QM/MM Models of the O2-Evolving Complex of Photosystem II", Eduardo M. Sproviero, José A. Gascón, James P. McEvoy, Gary W. Brudvig and Victor S. Batista (2006) J. Chem. Theory Comput. 2, 1119-1134.

185. "Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst", Siddhartha Das, Christopher D. Incarvito, Robert H. Crabtree and Gary W. Brudvig (2006) Science 312, 1941-1943.

184. "Secondary Bonding in a Six-Coordinate Mn(II) Complex as a Model for Associative Substitution", Clyde W. Cady, Christopher Incarvito, Gary W. Brudvig and Robert H. Crabtree  (2006) Inorg. Chim. Acta 359, 2509-2512.

183. "Characterization of Synthetic Oxomanganese Complexes and the Inorganic Core of the O2-Evolving Complex in Photosystem II:  Evaluation of the DFT/B3LYP Level of Theory", Eduardo M. Sproviero, José A. Gascón, James P. McEvoy, Gary W. Brudvig and Victor S. Batista (2006) J. Inorg. Biochem. 100, 786-800.

182. "A Multifrequency High-Field EPR (9-285 GHz) Investigation of a Series of Dichloride Mononuclear Pentacoordinated Mn(II) Complexes", Carole Duboc, Vincent Astier-Perret, Hongyu Chen, Jacques Pécaut, Robert H. Crabtree, Gary W. Brudvig and  Marie-Noëlle Collomb (2006) Inorg. Chim. Acta 359, 1541-1548.

181. "New Linear High-Valent Tetranuclear Manganese-Oxo Cluster Relevant to the Oxygen-Evolving Complex of Photosystem II with Oxo, Hydroxo and Aqua Coordination to a Single Mn(IV)", Hongyu Chen, Marie-Noëlle Collomb, Carole Duboc, Geneviève Blondin, Eric Rivière, J. W. Faller, Robert H. Crabtree and Gary W. Brudvig (2005) Inorg. Chem. 44, 9567-9573.

180. "Mechanistic Comparisons Between Photosystem II and Cytochrome c Oxidase", Gary W. Brudvig and Mårten Wikström (2005) in: "Photosystem II:  The Light-Driven Water:Plastoquinone Oxidoreductase" (T. J. Wydrzynski and K. Satoh, eds.) Springer Publishers, Dordrecht, The Netherlands, pp. 697-713.

179. "The Mechanism of Photosynthetic Water Splitting", James P. McEvoy, José A. Gascón, Victor S. Batista and Gary W. Brudvig (2005) Photochem. Photobiol. Sci. 4, 940-949.

178. "Construction and Characterization of Genetically Modified Synechocystis sp. PCC 6803 Photosystem II Core Complexes Containing Carotenoids with Shorter π-conjugation than β-carotene", James A. Bautista, Cara A. Tracewell, Eberhard Schlodder, Francis X. Cunningham, Jr., Gary W. Brudvig and Bruce A. Diner (2005) J. Biol. Chem. 280, 38839-38850.

177. "General Synthesis of Di-μ-oxo Dimanganese Complexes as Functional Models for the Oxygen-Evolving Complex of Photosystem II", Hongyu Chen, Ranitendranath Tagore, Siddhartha Das, Christopher Incarvito, J. W. Faller, Robert H. Crabtree and Gary W. Brudvig (2005) Inorg. Chem. 44, 7661-7670.

176. "The Mechanism of Photosynthetic Water Oxidation in the Light of New Structural Information", James P. McEvoy and Gary W. Brudvig (2005) in:  "Photosynthesis: Fundamental Aspects to Global Perspectives", Vol. 1 (A. van der Est and D. Bruce, eds.) Allen Press Inc., Lawrence, Kansas, pp. 339-344.

175. "Carotenoid Photooxidation and Charge Recombination in Photosystem II", Cara A. Tracewell and Gary W. Brudvig (2005) in:  "Photosynthesis: Fundamental Aspects to Global Perspectives", Vol. 1 (A. van der Est and D. Bruce, eds.) Allen Press Inc., Lawrence, Kansas, pp. 313-316.

174. "Computational Structural Model of the Oxygen Evolving Complex in Photosystem II: Complete Ligation by Protein, Water and Chloride", James P. McEvoy, José A. Gascón, Eduardo M. Sproviero, Victor S. Batista and Gary W. Brudvig (2005) in:  "Photosynthesis: Fundamental Aspects to Global Perspectives", Vol. 1 (A. van der Est and D. Bruce, eds.) Allen Press Inc., Lawrence, Kansas, pp. 278-280.

173. "A Comparative Study of the Arrangement of the Iron-Sulfur Clusters in Type I Reaction Centers from Cyanobacteria and Green Sulfur Bacteria", K. V. Lakshmi, Wade Johnson, John H. Golbeck and Gary W. Brudvig (2005) in:  "Photosynthesis: Fundamental Aspects to Global Perspectives", Vol. 1 (A. van der Est and D. Bruce, eds.) Allen Press Inc., Lawrence, Kansas, pp. 64-66.

172. "Catalytic Oxygen Evolution by a Bioinorganic Model of the Photosystem II Oxygen-Evolving Complex", Derrick L. Howard, Arthur D. Tinoco, Gary W. Brudvig, John S. Vrettos and Bertha Connie Allen (2005) J. Chem. Ed. 82, 791-794.

171. "High-Spin Chloro Mononuclear MnIII Complexes:  A Multifrequency High-Field EPR Study", Claire Mantel, Hongyu Chen, Robert H. Crabtree, Gary W. Brudvig, Jacques Pécaut, Marie-Noëlle Collomb and Carole Duboc (2005) Chem. Phys. Chem. 6, 541-546.

170. "Resonance Raman Spectroscopy of Carotenoids in Photosystem II Core Complexes", Cara A. Tracewell, Agnes Cua, David F. Bocian and Gary W. Brudvig (2005) Photosynth. Res. 83, 45-52.

169. "Investigation of the Functional Role of Ca2+ in the Oxygen-Evolving Complex of Photosystem II:  A pH-Dependence Study of the Substitution of Ca2+ by Sr2+", Cheng-I Lee and Gary W. Brudvig (2004) J. Chin. Chem. Soc. 51, 1221-1228.

168. "Structure-Based Mechanism of Photosynthetic Water Oxidation", James P. McEvoy and Gary W. Brudvig (2004) Phys. Chem. Chem. Phys. 6, 4754-4763.

167. "Q-band EPR of the S2 state of Photosystem II Confirms an S=5/2 Origin of the X-band g=4.1 Signal", Alice Haddy, K. V. Lakshmi, Gary W. Brudvig and Harry A. Frank (2004) Biophys. J. 87, 2885-2896.

166. "The FAD-Stacking Residue Phe1395 Regulates Neuronal Nitric Oxide Synthase Catalysis by Controlling NADP+ Affinity and a Conformational Equilibrium Within the Flavoprotein Domain", David W. Konas, Keng Zhu, Manisha Sharma, Kulwant S. Aulak, Gary W. Brudvig and Dennis J. Stuehr (2004) J. Biol. Chem. 279, 35412-35425.

165. "Location of EPR-Active Spins Buried in Proteins from Simulation of the Relaxation Enhancement Caused by Dy(III) Complexes", Ryan MacArthur and Gary W. Brudvig (2004) J. Phys. Chem. B 108, 9390-9396.

164. "Redox Functions of Carotenoids in Photosynthesis", Harry A. Frank and Gary W. Brudvig (2004) Biochemistry 43, 8607-8615.

163. "Dimer-of-Dimers Model for the Oxygen-Evolving Complex of Photosystem II.  Synthesis and Properties of [MnIV4O5(terpy)4(H2O)2](ClO4)6", Hongyu Chen, J. W. Faller, Robert H. Crabtree and Gary W. Brudvig (2004) J. Am. Chem. Soc.126, 7345-7349.

162.  "Oxygen Evolution", John S. Vrettos and Gary W. Brudvig (2004) in: "Comprehensive Coordination Chemistry II, From Biology to Nanotechnology", Volume 8 on Bio-coordination Chemistry (J. A. McCleverty and T. J. Meyer, eds. in chief;  L. Que, Jr. and W. B. Tolman, volume eds.) Elsevier, Amsterdam, The Netherlands, pp. 507-547.

161. "Two Redox-Active β-Carotene Molecules in Photosystem II", Cara A. Tracewell and Gary W. Brudvig (2003) Biochemistry 42, 9127-9136.

160. "Raman Spectra and Normal Coordinate Analyses of Low-Frequency Vibrations of Oxo-Bridged Manganese Complexes", Agnes Cua, John S. Vrettos, Julio C. de Paula, Gary W. Brudvig and David F. Bocian (2003) J. Biol. Inorg. Chem. 8, 439-451.

159. "The X-ray Structure of Photosystem II  Reveals a Novel Electron Transport Pathway Between P680, Cytochrome b559 and the Energy-Quenching Cation, ChlZ+", Sergej Vasil'ev, Gary W. Brudvig and Doug Bruce (2003) FEBS Lett. 543, 159-163.

158. "Pulsed High-Frequency EPR Study on the Location of Carotenoid and Chlorophyll Cation Radicals in Photosystem II", K. V. Lakshmi, Oleg G. Poluektov, Michael J. Reifler, Arlene M. Wagner, Marion C. Thurnauer and Gary W. Brudvig (2003) J. Am. Chem. Soc. 125, 5005-5014.

157. "Component B Binding to the Soluble Methane Monooxygenase Hydroxylase by Saturation-Recovery EPR Spectroscopy of Spin-Labeled MMOB", Ryan MacArthur, Matthew H. Sazinsky, Henriette Kühne, Douglas Whittington, Stephen J. Lippard and Gary W. Brudvig (2002) J. Am. Chem. Soc. 124, 13392-13393.

156.  "Water Oxidation Chemistry of Photosystem II", John S. Vrettos and Gary W. Brudvig (2002) Phil. Trans. R. Soc. Lond. B 357, 1395-1405.

155. "Structure-Based Kinetic Modeling of Excited-State Transfer and Trapping in His-Tagged Photosystem II Core Complexes fromSynechocystis PCC 6803", Sergei Vassiliev, Cheng-I Lee, Gary W. Brudvig and Doug Bruce (2002) Biochemistry 41, 12236-12243.

154. "Electronic Structure of the P700 Special Pair from High-Frequency EPR Spectroscopy", Oleg G. Poluektov, Lisa M. Utschig, Sandra L. Schlesselman, K. V. Lakshmi, Gary W. Brudvig, Gerd Kothe and Marion C. Thurnauer (2002) J. Phys. Chem. B 106, 8911-8916.

153. "Proton-Coupled Electron Transfer Involving Tyrosine Z of Photosystem II", Henriette Kühne and Gary W. Brudvig (2002) J. Phys. Chem. B 106, 8189-8196.

152. "Correlation of the Cytochrome c550 Content of Cyanobacterial Photosystem II with the EPR Properties of the Oxygen-Evolving Complex", K. V. Lakshmi, Michael J. Reifler, Dexter A. Chisholm, Jamie Y. Wang, Bruce A. Diner and Gary W. Brudvig (2002) Photosynth. Res. 72, 175-189.

151. "Two New Terpyridine Dimanganese Complexes: A Manganese(III,III) Complex with a Single Unsupported Oxo Bridge and a Manganese(III,IV) Complex with a Dioxo Bridge. Synthesis, Structure and Redox Properties", Carole Baffert, Marie-Noëlle Collomb, Alain Deronzier, Jacques Pécaut, Julian Limburg, Robert H. Crabtree and Gary W. Brudvig (2002) Inorg. Chem. 41, 1404-1411.

150. "Species Dependent Differences in the Secondary Electron-Donation Reactions of Photosystem II", C. A. Tracewell and G. W. Brudvig (2002) in:  "PS2001 Proceedings. 12th International Congress on Photosynthesis" CSIRO Publishers, S5-001.

149. "Pulsed Electron Paramagnetic Resonance Methods for Macromolecular Structure Determination", K. V. Lakshmi and Gary W. Brudvig (2001) Curr. Opin. Struct. Biol. 11, 523-531.

148. "Factors that Determine the Unusually Low Reduction Potential of Cytochrome c550 in Cyanobacterial Photosystem II", John S. Vrettos, Michael J. Reifler, Olaf Kievit, K. V. Lakshmi, Julio C. de Paula and Gary W. Brudvig (2001) J. Biol. Inorg. Chem. 6, 708-716.

147. "Photosynthetic Water Oxidation in Cytochrome b559 Mutants Containing a Disrupted Heme-Binding Pocket", Francisco Morais, Kristina Kühn, David H. Stewart, James Barber, Gary W. Brudvig and Peter J. Nixon (2001) J. Biol. Chem. 276, 31986-31993.

146. "Electrochemical Properties of [MnIII(terpy)(N3)3] (terpy = 2,2':6',2"-terpyridine) in CH3CN. Electrogeneration of Dimanganese(II) di-μ-azido and Dimanganese(IV) di-μ-oxo Complexes", Carole Baffert, Hongyu Chen, Robert H. Crabtree, Gary W. Brudvig and Marie-Noëlle Collomb (2001) J. Electroanal. Chem. 506, 99-105.

145. "Quantifying the Ion Selectivity of the Ca2+ Site in Photosystem II: Evidence for Direct Involvement of Ca2+ in O2 Formation", John S. Vrettos, Daniel A. Stone and Gary W. Brudvig (2001) Biochemistry 40, 7937-7945.

144. "Use of EPR Spectroscopy to Study Macromolecular Structure and Function", Roopa Biswas, Henriette Kühne, Gary W. Brudvig and Venkat Gopalan (2001) Science Progress 84, 45-68.

143. "Effects of Tail-Like Substituents on the Binding of Competitive Inhibitors to the QB Site of Photosystem II", Michael J. Reifler, Veronika A. Szalai, Celeste N. Peterson and Gary W. Brudvig (2001) J. Mol. Recognit. 14, 157-165.

142. "High-Frequency EPR Study of a New Mononuclear Manganese(III) Complex: [(terpy)MnIII(N3)3] (terpy = 2,2':6',2"-terpyridine)", Julian Limburg, John S. Vrettos, Robert H. Crabtree, Gary W. Brudvig, Julio C. de Paula, Alia Hassan, Anne-Laure Barra, Carole Duboc-Toia and Marie-Noëlle Collomb (2001) Inorg. Chem. 40, 1698-1703.

141. "Direct Electrochemistry of Photosystem I", Olaf Kievit and Gary W. Brudvig (2001) J. Electroanal. Chem. 497, 139-149.

140. "Characterization of the O2-Evolving Reaction Catalyzed by [(terpy)(H2O)MnIII(O)2MnIV(OH2)(terpy)](NO3)3 (terpy = 2,2':6',2"-terpyridine)", Julian Limburg, John S. Vrettos, Hongyu Chen, Julio C. de Paula, Robert H. Crabtree and Gary W. Brudvig (2001) J. Am. Chem. Soc. 123, 423-430.

139. "Characterization of Carotenoid and Chlorophyll Photooxidation in Photosystem II", Cara A. Tracewell, Agnes Cua, David H. Stewart, David F. Bocian and Gary W. Brudvig (2001) Biochemistry 40, 193-203.

138. "Carotenoid Photooxidation in Photosystem II", Cara A. Tracewell, John S. Vrettos, James A. Bautista, Harry A. Frank and Gary W. Brudvig (2001) Arch. Biochem. Biophys. 385, 61-69.

137. "Mechanism of Photosynthetic Water Oxidation: Combining Biophysical Studies of Photosystem II with Inorganic Model Chemistry", John S. Vrettos, Julian Limburg and Gary W. Brudvig (2001) Biochim. Biophys. Acta 1503, 229-245.

136. "Electron Paramagnetic Resonance Distance Measurements in Photosystems", K. V. Lakshmi and Gary W. Brudvig (2000) in: "Biological Magnetic Resonance", Vol. 19 (Lawrence J. Berliner, Sandra S. Eaton and Gareth R. Eaton, eds.)  Kluwer Academic/Plenum Publishers, New York, New York, pp. 513-567.

135. "Assignment of the Qy Absorbance Bands of Photosystem II Chromophores by Low Temperature Optical Spectroscopy of Wild-Type and Mutant Reaction Centers", David H. Stewart, Peter J. Nixon, Bruce A. Diner and Gary W. Brudvig (2000) Biochemistry 39, 14583-14594.

134. "High-Field EPR Study of Carotenoid and Chlorophyll Cation Radicals in Photosystem II", K. V. Lakshmi, Michael J. Reifler, Gary W. Brudvig, Oleg G. Poluektov, Arlene M. Wagner and Marion C. Thurnauer (2000) J. Phys. Chem. B 104, 10445-10448.

133. "Low-Temperature Turnover Control of Photosystem II Using Novel Metal-Containing Redox-Active Herbicides", Laba Karki, K. V. Lakshmi, Veronika A. Szalai and Gary W. Brudvig (2000) J. Am. Chem. Soc. 122, 5180-5188.

132. "Low-Frequency Resonance Raman Characterization of the Oxygen-Evolving Complex of Photosystem II", Agnes Cua, David H. Stewart, Michael J. Reifler, Gary W. Brudvig and David F. Bocian (2000) J. Am. Chem. Soc. 122, 2069-2077.

131. "Modeling the Oxygen-Evolving Complex in Photosystem II", Julian Limburg, Gary W. Brudvig and Robert H. Crabtree (2000) in: "Biomimetic Oxidations Catalyzed by Transition Metal Complexes" (B. Meunier, ed.) World Scientific Publishers, Singapore, pp. 509-541.

130. "Kinetic Analysis of the O2-Forming Reaction Between [MnIII(dpa)2]- (dpa = dipicolinate) and Potassium Peroxomonosulfate", Julian Limburg, Robert H. Crabtree and Gary W. Brudvig (2000) Inorg. Chim. Acta 297, 301-306.

129. "Location of the Iron-Sulfur Clusters FA and FB in Photosystem I: An Electron Paramagnetic Resonance Study of Spin Relaxation Enhancement of P700+", K. V. Lakshmi, Yean-Sung Jung, John H. Golbeck and Gary W. Brudvig (1999) Biochemistry 38, 13210-13215.

128. "Orientation of the Tetranuclear Manganese Cluster and Tyrosine Z in the O2-Evolving Complex of Photosystem II:  An EPR Study of the S2YZ. State in Oriented Acetate-Inhibited Photosystem II Membranes", K. V. Lakshmi, Sandra S. Eaton, Gareth R. Eaton and Gary W. Brudvig (1999) Biochemistry 38, 12758-12767.

127. "Low-Temperature Optical and Resonance Raman Spectra of a Carotenoid Cation Radical in Photosystem II", John S. Vrettos, David H. Stewart, Julio C. de Paula and Gary W. Brudvig (1999) J. Phys. Chem. B 103, 6403-6406.

126. "Competitive Binding of Chloride and Acetate in Photosystem II", Henriette Kühne, Veronika A. Szalai and Gary W. Brudvig (1999) Biochemistry 38, 6604-6613.

125. "A Mechanistic and Structural Model for the Formation and Reactivity of a MnV=O Species in Photosynthetic Water Oxidation", Julian Limburg, Veronika A. Szalai and Gary W. Brudvig (1999) J. Chem. Soc., Dalton Trans. 1353-1363.

124. "Selective Raman Scattering from the Core Chlorophylls in Photosystem I via Preresonant Near-Infrared Excitation", David H. Stewart, Agnes Cua, David F. Bocian and Gary W. Brudvig (1999) J. Phys. Chem. B 103, 3758-3764.

123. "A Functional Model for O-O Bond Formation by the O2-Evolving Complex in Photosystem II", Julian Limburg, John S. Vrettos, Louise M. Liable-Sands, Arnold L. Rheingold, Robert H. Crabtree and Gary W. Brudvig (1999) Science 283, 1524-1527.

122. "Mapping RNA-Protein Interactions in Ribonuclease P from Escherichia coli Using Electron Paramagnetic Resonance Spectroscopy", Venkat Gopalan, Henriette Kühne, Roopa Biswas, Huimei Li, Gary W. Brudvig and Sidney Altman (1999) Biochemistry 38, 1705-1714.

121. "Cytochrome b559 of Photosystem II", David H. Stewart and Gary W. Brudvig (1998) Biochim. Biophys. Acta 1367, 63-87.

120. "A Structural and Mechanistic Model of the O2-Evolving Complex Photosystem II", Veronika A. Szalai, Daniel A. Stone and Gary W. Brudvig (1998) in: "Photosynthesis:  Mechanisms and Effects", vol. 2, (G. Garab, ed.) Kluwer Academic Publishers, Dordrecht, The Netherlands, pp. 1403-1406.

119. "Engineering and Rapid Purification of Histidine-Tagged Photosystem II from Synechocystis PCC 6803", Michael J. Reifler, Dexter A. Chisholm, Jamie Wang, Bruce A. Diner and Gary W. Brudvig (1998) in: "Photosynthesis:  Mechanisms and Effects", vol. 2, (G. Garab, ed.) Kluwer Academic Publishers, Dordrecht, The Netherlands, pp. 1189-1192.

118. "A New Model of Cytochrome b559 Function Based on the Observation of a Reversible Redox-Linked Interconversion Between Two Redox Forms of Cytochrome b559", David H. Stewart and Gary W. Brudvig (1998) in: "Photosynthesis:  Mechanisms and Effects", vol. 2, (G. Garab, ed.) Kluwer Academic Publishers, Dordrecht, The Netherlands, pp. 1113-1116.

117. "Analysis of Dipolar and Exchange Interactions Between Manganese and Tyrosine Z in the S2YZ. State of Acetate-Inhibited Photosystem II via EPR Spectral Simulations at X- and Q-bands", K. V. Lakshmi, Sandra S. Eaton, Gareth R. Eaton, Harry A. Frank and Gary W. Brudvig (1998) J. Phys. Chem. B 102, 8327-8335.

116. "Time-Resolved Fluorescence Measurements of Photosystem II: The Effect of Quenching by Oxidized Chlorophyll Z", Robert H. Schweitzer, Alexander N. Melkozernov, Robert E. Blankenship and Gary W. Brudvig (1998) J. Phys. Chem. B 102, 8320-8326.

115. "How Plants Produce Dioxygen", Veronika A. Szalai and Gary W. Brudvig (1998) Amer. Sci. 86, 542-551.

114. "Characterization of the Interaction between Manganese and Tyrosine Z in Acetate-Inhibited Photosystem II", Veronika A. Szalai, Henriette Kühne, K. V. Lakshmi and Gary W. Brudvig (1998) Biochemistry 37, 13594-13603.

113. "Identification of Histidine 118 in the D1 Polypeptide of Photosystem II as the Axial Ligand to Chlorophyll Z", David H. Stewart, Agnes Cua, Dexter A. Chisholm, Bruce A. Diner, David F. Bocian and Gary W. Brudvig (1998) Biochemistry 37, 10040-10046.

112. "Selective Resonance Raman Scattering from Chlorophyll Z in Photosystem II via Excitation into the Near-Infrared Absorption Band of the Cation", Agnes Cua, David H. Stewart, Gary W. Brudvig and David F. Bocian (1998) J. Am. Chem. Soc. 120, 4532-4533.

111. "Catalase-Free Photosystem II: The O2-Evolving Complex does not Dismutate Hydrogen Peroxide", Yelena G. Sheptovitsky and Gary W. Brudvig (1998) Biochemistry 37, 5052-5059.

110. "Calcium Binding Studies of Photosystem II using a Calcium-Selective Electrode", Geoffrey N. Grove and Gary W. Brudvig (1998) Biochemistry 37, 1532-1539.

109. "Fluorescence Quenching by Chlorophyll Cations in Photosystem II", Robert H. Schweitzer and Gary W. Brudvig (1997) Biochemistry 36, 11351-11359.

108. "The Tetranuclear Manganese Cluster in Photosystem II: Location and Magnetic Properties of the S2 State as Determined by Saturation-Recovery EPR Spectroscopy", Dionysios Koulougliotis, Robert H. Schweitzer and Gary W. Brudvig (1997) Biochemistry36, 9735-9746.

107. "O2 Evolution and Permanganate Formation From High Valent Manganese Complexes", Julian Limburg, Gary W. Brudvig and Robert H. Crabtree (1997) J. Am. Chem. Soc. 119, 2761-2762.

106. "Isolation and Characterization of Spinach Photosystem II Membrane-Associated Catalase and Polyphenol Oxidase", Yelena G. Sheptovitsky and Gary W. Brudvig (1996) Biochemistry 35, 16255-16263.

105. "Reversible Binding of Nitric Oxide to Tyrosyl Radicals in Photosystem II. Nitric Oxide Quenches Formation of the S3 EPR Signal Species in Acetate-Inhibited Photosystem II", Veronika Szalai and Gary W. Brudvig (1996) Biochemistry 35, 15080-15087.

104. "Characterization of the Reductase Domain of Rat Neuronal Nitric Oxide Synthase Generated in the Methylotrophic Yeast Pichia pastoris. Calmodulin Response is Complete Within the Reductase Domain Itself", Ratan Gachhui, Anthony Presta, Dennis F. Bentley, Husam M. Abu-Soud, Ryan MacArthur, Gary W. Brudvig, Dipak K. Ghosh and Dennis J. Stuehr (1996) J. Biol. Chem. 271, 20594-20602.

103. "Synthesis and Characterization of an Internal Emission Standard and Applications to Fluorescence Studies of Photosystem II", Robert H. Schweitzer and Gary W. Brudvig (1996) Biospectroscopy 2, 167-171.

102. "Effects of Dipole-Dipole Interactions on Microwave Progressive Power Saturation of Radicals in Proteins", C. Galli, Jennifer B. Innes, Donald J. Hirsh and Gary W. Brudvig (1996) J. Magn. Res. B110, 284-287.

101. "EPR Spectroscopic Characterization of Neuronal NO Synthase", Chris Galli, Ryan MacArthur, Husam M. Abu-Soud, Pamela Clark, Dennis J. Stuehr and Gary W. Brudvig (1996) Biochemistry 35, 2804-2810.

100. "Formation and Decay of the S3 EPR Signal in Acetate-Inhibited Photosystem II", Veronika Szalai and Gary W. Brudvig (1996) Biochemistry 35, 1946-1953.

99. "Parallel Low-Temperature Fluorescence and EPR Measurements on Mn-Depleted Photosystem II", Robert H. Schweitzer and Gary W. Brudvig (1995) in: "Photosynthesis: From Light to Biosphere", vol. 1, (P. Mathis, ed.) Kluwer Academic Publishers, Dordrecht, The Netherlands, pp. 807-810.

98. "Structure and Function of Manganese in Photosystem II", Gary W. Brudvig (1995) Adv. Chem. Series 246, 249-263.

97. "High-Valent Oxomanganese Clusters: Structural and Mechanistic Work Relevant to the Oxygen-Evolving Center in Photosystem II", Rajesh Manchanda, Gary W. Brudvig and Robert H. Crabtree (1995) Coord. Chem. Rev. 144, 1-38.

96. "Electron Paramagnetic Resonance Spectroscopy", Gary W. Brudvig (1995) Meth. Enzymol. 246, 536-554.

95. "A (μ-Oxo)bis(μ-Carboxylato)diiron(III) Complex with a Tethered Phenoxyl Radical as a Model for the Active Site of the R2 Protein of Ribonucleotide Reductase", David P. Goldberg, Dionysios Koulougliotis, Gary W. Brudvig and Stephen J. Lippard (1995) J. Am. Chem. Soc. 117, 3134-3144.

94. "Spectroscopic Evidence for the Symmetric Location of Tyrosines D and Z in Photosystem II", Dionysios Koulougliotis, Xiao-Song Tang, Bruce A. Diner and Gary W. Brudvig (1995) Biochemistry 34, 2850-2856.

93. "Variations in the Diferric Exchange Coupling in the R2 Subunit of Ribonucleotide Reductase from Four Species as Determined by Saturation-Recovery EPR Spectroscopy", C. Galli, Mohamed Atta, K. Kristoffer Andersson, Astrid Gräslund and Gary W. Brudvig (1995) J. Am. Chem. Soc. 117, 740-746.

92. "Location of ChlorophyllZ in Photosystem II", Dionysios Koulougliotis, Jennifer B. Innes and Gary W. Brudvig (1994) Biochemistry 33, 11814-11822.

91. "Improved Syntheses and Structure of [MnIIIMnIV(O)2(phen)4](ClO4)3.2CH3COOH.2H2O", Rajesh Manchanda, Gary W. Brudvig, Susan de Gala and Robert H. Crabtree (1994) Inorg. Chem. 33, 5157-5160.

90. "A Modified MM2 Force Field for High-Valent Di-μ-Oxo Manganese Dimers", Rajesh Manchanda, Marc Zimmer, Gary W. Brudvig and Robert H. Crabtree (1994) J. Mol. Struct. 323, 257-266.

89. "Cluster Expansion of a High-Valent Oxomanganese Dimer in Aqueous Solution", Rajesh Manchanda, Gary W. Brudvig and Robert H. Crabtree (1994) New J. Chem. 18, 561-568.

88. "Chemical Oxidation and Reduction of the O2-Evolution Center of Photosystem II", Chao Lin and Gary W. Brudvig (1993) Photosynth. Res. 38, 441-448.

87. "Long Range Electron Spin-Spin Interactions in the Bacterial Photosynthetic Reaction Center", Donald J. Hirsh and Gary W. Brudvig (1993) J. Phys. Chem. 97, 13216-13222.

86. "Spectroscopic Evidence from Site-Directed Mutants of Synechocystis PCC6803 in Favor of a Close Interaction Between Histidine 189 and Redox-Active Tyrosine 160, Both of Polypeptide D2 of the Photosystem II Reaction Center", Xiao-Song Tang, Dexter A. Chisholm, G. Charles Dismukes, Gary W. Brudvig and Bruce A. Diner (1993) Biochemistry 32, 13742-13748.

85. "Formation of a High Valent Di-μ-oxo Manganese Dimer in Aqueous Solution", Rajesh Manchanda, Gary W. Brudvig, Robert H. Crabtree, Joseph E. Sarneski and Mary Didiuk (1993) Inorg. Chim. Acta 212, 135-137.

84.  "A Study of High-Valent Manganese in Aqueous H3PO4: Disproportionation of [MnIIIMnIV(μ-O)2(bpy)4]3+", Joseph E. Sarneski, Linda J. Brzezinski, Brandon Anderson, Mary Didiuk, Rajesh Manchanda, Robert H. Crabtree, Gary W. Brudvig and Gayle K. Schulte (1993) Inorg. Chem. 32, 3265-3269.

83. "pH Dependence of the Dark Redox State and Photooxidation of YD in O2-Evolving PSII-Enriched Membranes", Carolyn A. Buser and Gary W. Brudvig (1992) in: "Research in Photosynthesis", vol. 2, (N. Murata, ed.) Kluwer Academic Publishers, Dordrecht, The Netherlands, pp. 817-820.

82. "Turnover Control of Photosystem II: Use of Redox-Active Herbicides to Form the S3 State", Jeffrey R. Bocarsly and Gary W. Brudvig (1992) J. Am. Chem. Soc. 114, 9762-9767.

81. "Photooxidation of Cytochrome b559 in Oxygen-Evolving Photosystem II", Carolyn A. Buser, Bruce A. Diner and Gary W. Brudvig (1992) Biochemistry 31, 11449-11459.

80. "Reevaluation of the Stoichiometry of Cytochrome b559 in Photosystem II and Thylakoid Membranes", Carolyn A. Buser, Bruce A. Diner and Gary W. Brudvig (1992) Biochemistry 31, 11441-11448.

79. "An Unusual Example of Multiple Proton-Coupled Electron Transfers in a High-Valent Oxomanganese Dimer, [(phen)2MnIII(O)2MnIV(phen)2](ClO4)3 (phen=1,10 Phenanthroline)", Rajesh Manchanda, H. Holden Thorp, Gary W. Brudvig and Robert H. Crabtree (1992) Inorg. Chem. 31, 4040-4041.

78.  "The O2-Evolving Center of Photosystem II is Diamagnetic in the S1 Resting State", Dionysios Koulougliotis, Donald J. Hirsh and Gary W. Brudvig (1992) J. Am. Chem. Soc. 114, 8322-8323.

77. "Using Saturation-Recovery EPR to Measure Exchange Couplings in Proteins: Applications to Ribonucleotide Reductase", Donald J. Hirsh, Warren F. Beck, John B. Lynch, Lawrence Que, Jr. and Gary W. Brudvig (1992) J. Am. Chem. Soc. 114, 7475-7481.

76. "Calcium Binding Site(s) of Photosystem II as Probed by Lanthanides", Alexandra Bakou, Carolyn Buser, Gregory Dandoulakis, Gary Brudvig and Demetrios F. Ghanotakis (1992) Biochim. Biophys. Acta 1099, 131-136.

75. "Towards a Functional Model of Hydrogenase: Electrocatalytic Reduction of Protons to Dihydrogen by a Nickel Macrocyclic Complex", Laura L. Efros, H. Holden Thorp, Gary W. Brudvig and Robert H. Crabtree (1992) Inorg. Chem. 31, 1722-1724.

74. "Using Saturation-Recovery EPR to Measure Distances in Proteins: Applications to Photosystem II", Donald J. Hirsh, Warren F. Beck, Jennifer B. Innes and Gary W. Brudvig (1992) Biochemistry 31, 532-541.

73. "Oxidation-Reduction and Ligand-Substitution Reactions of the Oxygen-Evolving Center of Photosystem II", Gary W. Brudvig and Warren F. Beck (1992) in: "Manganese Redox Enzymes" (V.L. Pecoraro, ed.) VCH Publishers, New York, pp. 119-140.

72. "Probing the Mechanism of Water Oxidation in Photosystem II", Gary W. Brudvig, H. Holden Thorp and Robert H. Crabtree (1991) Accts. Chem. Res. 24, 311-316.

71. "Temperature-Dependent Cyclic Voltametry of Oxo-Bridged Dimers of Relevance to Photosynthetic Water Oxidation", William A. Kalsbeck, H. Holden Thorp and Gary W. Brudvig (1991) J. Electroanal. Chem. Interfacial Electrochem. 314, 335-343.

70. "Mechanism of Irreversible Inhibition of O2 Evolution in Photosystem II by Tris(hydroxymethyl)aminomethane", Keith W. Rickert, Jonathan Sears, Warren F. Beck and Gary W. Brudvig (1991) Biochemistry 30, 7888-7894.

69. "A High-Valent Oxomanganese Dimer Containing Bridging and Terminal Inorganic Phosphate Ligands", Joseph E. Sarneski, Mary Didiuk, H. Holden Thorp, Robert H. Crabtree, Gary W. Brudvig, J.W. Faller and Gayle K. Schulte (1991) Inorg. Chem. 30, 2833-2835.

68. "The Physical Inorganic Chemistry of Manganese Relevant to Photosynthetic Oxygen Evolution", H. Holden Thorp and Gary W. Brudvig (1991) New J. Chem. 15, 479-490.

67. "Electronic Structure of trans-Dioxorhenium(VI)", John C. Brewer, H. Holden Thorp, Kirby M. Slagle, Gary W. Brudvig and Harry B. Gray (1991) J. Am. Chem. Soc. 113, 3171-3173.

66. "Alkyl Hydroperoxide Oxidation of Alkanes and Alkenes with a Highly Active Mn Catalyst", Joseph E. Sarneski, Demetrios Michos, H. Holden Thorp, Mary Didiuk, Thomas Poon, Jennifer Blewitt, Gary W. Brudvig and Robert H. Crabtree (1991) Tetrahedron Lett.32, 1153-1156.

65. "Physical Properties of a Manganese Tetramer with All-Oxygen Coordination", H. Holden Thorp, Joseph E. Sarneski, Robert J. Kulawiec, Gary W. Brudvig, Robert H. Crabtree and G. Papaefthymiou (1991) Inorg. Chem. 30, 1153-1155.

64. "Proton-Coupled Electron Transfer in High-Valent Oxomanganese Clusters. Role of the Ancillary Ligands", Rajesh Manchanda, H. Holden Thorp, Gary W. Brudvig and Robert H. Crabtree (1991) Inorg. Chem. 30, 494-498.

63. "A Guide to Electron Paramagnetic Resonance Spectroscopy of Photosystem II Membranes", Anne-Frances Miller and Gary W. Brudvig (1991) Biochim. Biophys. Acta. 1056, 1-18.

62. "Electron Spin-Lattice Relaxation and Spectral Diffusion Measurements on Tyrosine Radicals in Proteins", Warren F. Beck, Jennifer B. Innes, John B. Lynch and Gary W. Brudvig (1991) J. Mag. Res. 91, 12-29.

61. "Proton-Coupled Electron Transfer in [(bpy)2Mn(O)2Mn(bpy)2]3+. Role of the Electrode Surface", H. Holden Thorp, Gary W. Brudvig and Edmond F. Bowden (1990) J. Electroanal. Chem. Interfacial Electrochem. 290, 293-301.

60. "Electron-Transfer Reactions in Manganese-Depleted Photosystem II", Carolyn A. Buser, Lynmarie K. Thompson, Bruce A. Diner and Gary W. Brudvig (1990) Biochemistry 29, 8977-8985.

59. "Assembly of High-Valent Oxomanganese Clusters in Aqueous Solution. Redox Equilibrium of Water-Stable Mn3O44+ and Mn2O23+Complexes", Joseph E. Sarneski, H. Holden Thorp, Gary W. Brudvig, Robert H. Crabtree and Gayle K. Schulte (1990) J. Am. Chem. Soc. 112, 7255-7260. (erratum: (1992) J. Am. Chem. Soc. 114, 5907.)

58. "Electron-Transfer Events Leading to Reconstitution of Oxygen Evolution Activity in Manganese-depleted Photosystem II", Anne-Frances Miller and Gary W. Brudvig (1990) Biochemistry 29, 1385-1392.

57. "Electron Spin-Lattice Relaxation of the Stable Tyrosine Radical in Photosystem II", Warren F. Beck, Jennifer B. Innes and Gary W. Brudvig (1990) in: "Current Research in Photosynthesis", vol. 1, (M. Baltscheffsky, ed.) Kluwer Academic Publishers, Dordrecht, The Netherlands, pp. 817-820.

56. "Coupling of the PS2 Reaction Center to the Oxygen-Evolving Center Requires a Very High Affinity Ca2+ Site", Katerina Kalosaka, Warren F. Beck, Gary Brudvig and George Cheniae (1990) in: "Current Research in Photosynthesis", vol. 1, (M. Baltscheffsky, ed.) Kluwer Academic Publishers, Dordrecht, The Netherlands, pp. 721-724.

55. "Proton-Coupled Electron Transfer in [(bpy)2Mn(O)2Mn(bpy)2]3+", H. Holden Thorp, Joseph E. Sarneski, Gary W. Brudvig and Robert H. Crabtree (1989) J. Am. Chem. Soc. 111, 9249-9250.

54. "EPR Spectroscopy of Manganese Enzymes", Gary W. Brudvig (1989) in: "Advanced EPR. Applications in Biology and Biochemistry" (A.J. Hoff, ed.) Elsevier, Amsterdam, pp. 839-863.

53. "Chloride Binding to Photosystem II in the Dark is in Slow Exchange", Yair Shachar-Hill, Warren F. Beck and Gary W. Brudvig (1989) FEBS Lett. 254, 184-188.

52. "Manganese and Calcium Requirements for Reconstitution of Oxygen-Evolution Activity in Manganese-Depleted Photosystem II Membranes", Anne-Frances Miller and Gary W. Brudvig (1989) Biochemistry 28, 8181-8190.

51. "Characterization of the Multiple Forms of Cytochrome b559 in Photosystem II", Lynmarie K. Thompson, Anne-Frances Miller, Carolyn A. Buser, Julio C. de Paula and Gary W. Brudvig (1989) Biochemistry 28, 8048-8056.

50. "Directed Alteration of the D1 Polypeptide of Photosystem II: Evidence that Tyr-161 is the Redox Component, Z, Connecting the Oxygen-Evolving Complex to the Primary Electron Donor, P680", James G. Metz, Peter J. Nixon, Matthias Rögner, Gary W. Brudvig and Bruce A. Diner (1989) Biochemistry 28, 6960-6969.

49. "Molecular Basis of the Heat Denaturation of Photosystem II", Lynmarie K. Thompson, Richard Blaylock, Julian M. Sturtevant and Gary W. Brudvig (1989) Biochemistry 28, 6686-6695.

48. "Oxidation of Exogenous Substrates by the O2-Evolving Center of Photosystem II and Related Catalytic Air Oxidation of Secondary Alcohols via a Tetranuclear Manganese(IV) Complex", Warren F. Beck, Jonathan Sears, Gary W. Brudvig, Robert J. Kulawiec and Robert H. Crabtree (1989) Tetrahedron 45, 4903-4911.

47. "Mechanism of Photosynthetic Water Oxidation", Gary W. Brudvig, Warren F. Beck and Julio C. de Paula (1989) Annu. Rev. Biophys. Biophys. Chem. 18, 25-46.

46. "Bioinorganic Chemistry of Manganese Related to Photosynthetic Oxygen Evolution", Gary W. Brudvig and Robert H. Crabtree (1989) Prog. Inorg. Chem. 37, 99-142.

45. "Location and Magnetic Relaxation Properties of the Stable Tyrosine Radical in Photosystem II", Jennifer B. Innes and Gary W. Brudvig (1989) Biochemistry 28, 1116-1125.

44. "Electron Transport in Photosystem II", Lynmarie K. Thompson, Anne-Frances Miller, Julio C. de Paula and Gary W. Brudvig (1988) Israel J. Chem. 28, 121-128.

43. "Cytochrome b559 May Function to Protect Photosystem II from Photoinhibition", Lynmarie K. Thompson and Gary W. Brudvig (1988) Biochemistry 27, 6653-6658.

42. "Modeling the Oxygen-Evolving Center of Photosystem II: Synthesis and Characterization of a Tetranuclear Manganese Carboxylate Complex", Robert J. Kulawiec, Robert H. Crabtree, Gary W. Brudvig and Gayle K. Schulte (1988) Inorg. Chem. 27, 1309-1311.

41. "Involvement of Manganese in Photosynthetic Water Oxidation", Gary W. Brudvig (1988) ACS Symposium Series 372, 221-237.

40. "Ligand-Substitution Reactions of the O2-Evolving Center of Photosystem II", Warren F. Beck and Gary W. Brudvig (1988) Chemica Scripta 28A, 93-98.

39. "Resolution of the Paradox of Ammonia and Hydroxylamine as Substrate Analogs for the Water Oxidation Reaction Catalyzed by Photosystem II", Warren F. Beck and Gary W. Brudvig (1988) J. Am. Chem. Soc. 110, 1517-1523.

38. "Reactions of Hydroxylamine with the Electron-Donor Side of Photosystem II", Warren F. Beck and Gary W. Brudvig (1987) Biochemistry 26, 8285-8295.

37. "Studies of the Manganese Site of Photosystem II by Electron Spin Resonance Spectroscopy", Julio C. de Paula, Warren F. Beck, Anne-Frances Miller, Robert B. Wilson and Gary W. Brudvig (1987) J. Chem. Soc., Faraday Trans. 1 83, 3635-3651.

36. "Formation of the S2 State and Structure of the Mn Complex in Photosystem II Lacking the Extrinsic 33 Kilodalton Polypeptide", Anne-Frances Miller, Julio C. de Paula and Gary W. Brudvig (1987) Photosynth. Res. 12, 205-218.

35. "Cytochrome b559 Plays a Structural Role in the Oxygen-Evolving Complex of Photosystem II", Lynmarie K. Thompson, Julian M. Sturtevant and Gary W. Brudvig (1987) in: "Progress in Photosynthesis Research", vol. 1, (J. Biggins, ed.) Martinus Nijhoff Publishers, The Hague, The Netherlands, pp. 609-612.

34. "Effect of Release of the 17 and 23 kDa Polypeptides of Photosystem II on Cytochrome b559", Julio C. de Paula, Brian W. Wu and Gary W. Brudvig (1987) in: "Progress in Photosynthesis Research", vol. 1, (J. Biggins, ed.) Martinus Nijhoff Publishers, The Hague, The Netherlands, pp. 605-608.

33. "The 33 kDa Extrinsic Polypeptide of Photosystem II is not a Ligand to Manganese in the O2-evolving Complex", Anne-Frances Miller, Julio C. de Paula and Gary W. Brudvig (1987) in: "Progress in Photosynthesis Research", vol. 1, (J. Biggins, ed.) Martinus Nijhoff Publishers, The Hague, The Netherlands, pp. 601-604.

32. "Coordination of Ammonia, but not Larger Amines, to the Manganese Site of the O2-evolving Center in the S2 State", Warren F. Beck and Gary W. Brudvig (1987) in: "Progress in Photosynthesis Research", vol. 1, (J. Biggins, ed.) Martinus Nijhoff Publishers, The Hague, The Netherlands, pp. 499-502.

31. "On the Mechanism of Photosynthetic Water Oxidation", Gary W. Brudvig and Julio C. de Paula (1987) in: "Progress in Photosynthesis Research", vol. 1, (J. Biggins, ed.) Martinus Nijhoff Publishers, The Hague, The Netherlands, pp. 491-498.

30. "Structure and Function of Manganese in Photosynthetic Water Oxidation", Julio C. de Paula, Warren F. Beck and Gary W. Brudvig (1987) New J. Chem. 11, 103-107.

29. "The Tetranuclear Manganese Complex of Photosystem II", Gary W. Brudvig (1987) J. Bioenerg. Biomembr. 19, 91-104.

28. "Effect of the 17 and 23 Kilodalton Polypeptides, Calcium, and Chloride on Electron Transfer in Photosystem II", Julio C. de Paula, Peter Mark Li, Anne-Frances Miller, Brian W. Wu and Gary W. Brudvig (1986) Biochemistry 25, 6487-6494.

27. "Binding of Amines to the O2-evolving Center of Photosystem II", Warren F. Beck and Gary W. Brudvig (1986) Biochemistry 25, 6479-6486.

26. "Differential Scanning Calorimetric Studies of Photosystem II: Evidence for a Structural Role for Cytochrome b559 in the Oxygen-evolving Complex", Lynmarie K. Thompson, Julian M. Sturtevant and Gary W. Brudvig (1986) Biochemistry 25, 6161-6169.

25. "Ammonia Binds to the Manganese Site of the O2-evolving Complex of Photosystem II in the S2 State", Warren F. Beck, Julio C. de Paula and Gary W. Brudvig (1986) J. Am. Chem. Soc. 108, 4018-4022.

24. "Magnetic Properties of Manganese in the Photosynthetic O2-evolving Complex. 2. Evidence for a Manganese Tetramer", Julio C. de Paula, Warren F. Beck and Gary W. Brudvig (1986) J. Am. Chem. Soc. 108, 4002-4009. (erratum: (1987) J. Am. Chem. Soc. 109, 6565.)

23. "Mechanism for Photosynthetic O2 Evolution", Gary W. Brudvig and Robert H. Crabtree (1986) Proc. Natl. Acad. Sci. U.S.A. 83, 4586-4588.

22. "A Comparison of an Exchange-coupled Fe(III)-Cu(II) Model with a Fe(IV) Model for the O2 binding Site in Oxidized Cytochromec Oxidase via EPR Spectral Simulations", Gary W. Brudvig, Randall H. Morse and Sunney I. Chan (1986) J. Mag. Res. 67, 189-201.

21. "Electron Transfer in Photosystem II at Cryogenic Temperatures", Julio C. de Paula, Jennifer B. Innes and Gary W. Brudvig (1985) Biochemistry 24, 8114-8120.

20. "Active and Resting States of the O2-evolving Complex of Photosystem II", Warren F. Beck, Julio C. de Paula and Gary W. Brudvig (1985) Biochemistry 24, 3035-3043.

19. "Magnetic Properties of Manganese in the Photosynthetic O2-evolving Complex", Julio C. de Paula and Gary W. Brudvig (1985) J. Am. Chem. Soc. 107, 2643-2648.

18. "Electron Spin Relaxation of CuA and Cytochrome a in Cytochrome c Oxidase Comparison to Heme, Copper, and Sulfur Radical Complexes", Gary W. Brudvig, David F. Blair and Sunney I. Chan (1984) J. Biol. Chem. 259, 11001-11009.

17. "The Metal Centers of Cytochrome c Oxidase: Structure and Function", Sunney I. Chan, Craig T. Martin, Hsin Wang, David F. Blair, Jeff Gelles, Gary W. Brudvig and Tom H. Stevens (1984) in: "Biochemical and Biophysical Studies of Proteins and Nucleic Acids" (T.-B. Lo, T.-Y. Liu and C.-H. Li, eds.) Elsevier Publishing Co., Amsterdam, pp. 219-239.

16. "Properties of the S2 State Associated with O2 Evolution", Gary W. Brudvig, John L. Casey and Kenneth Sauer (1983) in: "The Oxygen Evolving System of Photosynthesis" (Y. Inoue, A.R. Crofts, Govindjee, N. Murata, G. Renger and K. Satoh, eds.) Academic Press, Tokyo, pp. 159-164.

15. "The Effect of Temperature on the Formation and Decay of the Multiline EPR Signal Species Associated with Photosynthetic Oxygen Evolution", Gary W. Brudvig, John L. Casey and Kenneth Sauer (1983) Biochim. Biophys. Acta 723, 366-371.

14. "The Structure of the Metal Centers in Cytochrome c Oxidase", Sunney I. Chan, Craig T. Martin, Hsin Wang, Gary W. Brudvig and Tom H. Stevens (1983) in: "The Coordination Chemistry of Metalloenzymes. The Role of Metals in Reactions Involving Water, Dioxygen, and Related Species" (I. Bertini, R.S. Drago and C. Luchinat, eds.) D. Reidel Publishing Co., Dordrecht, Holland, pp. 313-328.

13. "Procedure for Rapid Isolation of Photosynthetic Reaction Centers Using Cytochrome c Affinity Chromatography", Gary W. Brudvig, Stephen T. Worland and Kenneth Sauer (1983) Proc. Natl. Acad. Sci. U.S.A. 80, 683-686.

12. "The Metal Centers in Cytochrome c Oxidase: Structures and Interactions", David F. Blair, Craig T. Martin, Jeff Gelles, Hsin Wang, Gary W. Brudvig, Tom H. Stevens and Sunney I. Chan (1983) Chemica Scripta 21, 43-53.

11. "The Nature of CuA in Cytochrome c Oxidase", Tom H. Stevens, Craig T. Martin, Hsin Wang, Gary W. Brudvig, Charles P. Scholes and Sunney I. Chan (1982) J. Biol. Chem. 257, 12106-12113.

10. "The Nature and Distribution of the Metal Centers in Cytochrome c Oxidase", Sunney I. Chan, Gary W. Brudvig, Craig T. Martin and Tom H. Stevens (1982) in: "Electron Transport and Oxygen Utilization" (C. Ho, ed.) Elsevier Publishing Co., Amsterdam, pp. 171-177.

9. "Conformations of Oxidized Cytochrome c Oxidase", Gary W. Brudvig, Tom H. Stevens, Randall H. Morse and Sunney I. Chan (1981) Biochemistry 20, 3912-3921.

8. "Reactions of Nitric Oxide with Cytochrome c Oxidase", Gary W. Brudvig, Tom H. Stevens and Sunney I. Chan (1980) Biochemistry 19, 5275-5285.

7. "The Structure of the Cytochrome a3-Cua3 Site in Cytochrome c Oxidase", Sunney I. Chan, Tom H. Stevens, Gary W. Brudvig and David F. Bocian (1980) Dev. Biochem. 10, 117-129.

6. "Evidence for the Absence of Photoreduction of the Metal Centers of Cytochrome c Oxidase by X-irradiation", Gary W. Brudvig, David F. Bocian, Ronald C. Gamble and Sunney I. Chan (1980) Biochim. Biophys. Acta 624, 78-89.

5. "Cua3 of Cytochrome c Oxidase is not a Type 1 (Blue) Copper", Gary W. Brudvig and Sunney I. Chan (1979) FEBS Lett. 106, 139-141.

4. "Resonance Raman Spectra of Cytochrome c Oxidase. Excitation in the 600 nm Region", David F. Bocian, Ann T. Lemly, Nils O. Petersen, Gary W. Brudvig and Sunney I. Chan (1979) Biochemistry 18, 4396-4402.

3. "Structure of the Cytochrome a3-Cua3 Couple in Cytochrome c Oxidase as Revealed by Nitric Oxide Binding Studies", Tom H. Stevens, Gary W. Brudvig, David F. Bocian and Sunney I. Chan (1979) Proc. Natl. Acad. Sci. U.S.A. 76, 3320-3324.

2. "The Nature of the "Visible" Copper in Cytochrome c Oxidase", Sunney I. Chan, David F. Bocian, Gary W. Brudvig, Randall H. Morse and Tom H. Stevens (1979) in: "Cytochrome Oxidase" (T.E. King, Y. Orii, B. Chance and K. Okunuki, eds.) Elsevier Publishing Co., Amsterdam, pp. 177-188.

1. "A Model for the "Visible" Copper in Cytochrome c Oxidase", Sunney I. Chan, David F. Bocian, Gary W. Brudvig, Randall H. Morse and Tom H. Stevens (1978) in: "Frontiers of Biological Energetics", vol. 2 (P.L. Dutton, J. Leigh, Jr. and A. Scarpa, eds.) Academic Press, New York, pp. 883-888.